dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

Base Information

Chemical Name:dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate
CAS No.:127628-16-4
Molecular Formula:C₂₇H₃₆N₂O₇SSi
Molecular Weight:560.744
Hs Code.:

Synonyms:dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

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Chemical Property of dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

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Technology Process of dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

There total 3 articles about dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 76513-69-4
(2-trimethylethylsilylethoxy)methyl chloride

: 127628-10-8
dimethyl (2S,3aR,8aS)-8-p-tolylsulphonyl-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

: 127628-16-4
dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; 1.) -78 deg C;
DOI:10.1039/c39890001418

Reference yield:

: 66377-68-2,79631-04-2,58635-46-4
N-(methoxycarbonyl)-L-tryptophan methyl ester

: 127628-16-4
dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / 85percent phosphoric acid

2: 85 percent / pyridine

3: 78 percent / 1.) lithium di-isopropylamide / tetrahydrofuran / 1.) -78 deg C

With pyridine; phosphoric acid; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1039/c39890001418

Reference yield:

: 79465-82-0
L-(2β,3aα,8aα)-1,2,3,3a,8,8a-hexahydro-1,2-dimethoxycarbonylpyrrolo<2,3-b>indole

: 127628-16-4
dimethyl (2S,3aR,8aS)-8-(p-tolylsulphonyl)-2-(2-trimethylsilylethoxymethyl)-1,2,3,3a,8,8a-hexahydropyrrolo<2,3-b>indole-1,2-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / pyridine

2: 78 percent / 1.) lithium di-isopropylamide / tetrahydrofuran / 1.) -78 deg C

With pyridine; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1039/c39890001418