2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride

Base Information

• Chemical Name: 2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride
• CAS No.: 392292-96-5
• Molecular Formula: C₃₃H₄₃ClCoN₃
• Molecular Weight: 576.171

Synonyms:2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride

Chemical Property of 2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride

Chemical Property:

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Technology Process of 2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride

There total 6 articles about 2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride (308359-86-6,207129-97-3) → 2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride (392292-96-5)

Guidance literature:

With zinc; In toluene; (N2); using Schlenk techniques; heating of suspn. of CoCl2(C5H3N(C(Me)NC6H3(CHMe2)2)2) and zinc powder in toluene at 50°C for 15 h; filtration, removal of volatiles under reduced pressure, recrystn. from toluene/pentane, elem. anal.;

DOI:10.1021/om049032b

Reference yield: 56.0%

2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride (308359-86-6,207129-97-3) → [bis(2,6-diisopropylphenylimino-κN,N'-ethyl)pyridine-κN]CoCl (392292-96-5)

Guidance literature:

With [((butadiene-magnesium)2THF)](n); In toluene; (Ar); a mixt. of Co complex and Mg compd. cooled to -78°C, precooled toluene added slowly, allowed to warm to room temp., stirred for 12 h; evapd. (vac.), taken up in toluene, filtered through deactivated silica gel, evapd. (vac.), recrystd. from toluene at -30°C; elem. anal.;

DOI:10.1021/ja052129k

Reference yield:

C33H43N3*2Cl(1-)*Co(2+) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 2,6-bis[1-(2,6-diispropylphenylimino)ethyl]pyridine cobalt(I) chloride (392292-96-5)

Guidance literature:

With tetrabutylammonium triphenyldifluorosilicate; In tetrahydrofuran; Inert atmosphere;

DOI:10.1021/acs.orglett.8b03986

upstream raw materials:

2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride

4-chlorobenzotrifluoride

[Co(2,6-bis(2,6-diisopropylphenyliminoethyl)pyridine)(CH₂SiMe₃)]

nitrogen

Downstream raw materials:

[Co(CH₂C₆H₅)(C₅H₃N(C(CH₃)N(C₆H₃(CH(CH₃)2)2))2)]

2,6-[2,6-(iPr)2C₆H₃NCMe]2C₅H₃NCoCH₂SiMe₃

[CoMe(2,6-(MeCN(2,6-(CHMe₂)2C₆H₃))2C₅H₃N)]

[i-PrPDI]CoBr

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