Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

Base Information

Chemical Name:Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside
CAS No.:161606-73-1
Molecular Formula:C₂₁H₂₃NO₇
Molecular Weight:401.416
Hs Code.:

Synonyms:Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

Suppliers and Price of Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

There total 4 articles about Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 161606-72-0
Methyl 3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

: 62-23-7
4-nitro-benzoic acid

: 161606-73-1
Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In benzene; at 20 ℃; for 2h;
DOI:10.1021/jo00106a035

Reference yield:

: 105454-48-6
3-O-Benzyl-2-deoxy-5-(triphenylmethyl)-D-erythro-pentofuranoside

: 161606-73-1
Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1: methanolic HCl / 3.5 h / 20 °C

2: 1.) (COCl)2, DMSO, 2.) NEt₃ / 1.) CH₂Cl₂, ca. -50 deg C, 15 min, 2.) ca. -50 deg C to 20 deg C

3: diethyl ether / -70 °C

4: 81 percent / Ph₃P, DEAD / benzene / 2 h / 20 °C

With hydrogenchloride; oxalyl dichloride; dimethyl sulfoxide; triethylamine; triphenylphosphine; diethylazodicarboxylate; In diethyl ether; benzene;
DOI:10.1021/jo00106a035

Reference yield:

: 113666-60-7
methyl 2-deoxy-3-O-benzyl-β-D-erythro-pentofuranoside

: 161606-73-1
Methyl 3-O-benzyl-2,6-dideoxy-5-O-(4-nitrobenzoyl)-α-L-lyxo-hexofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) (COCl)2, DMSO, 2.) NEt₃ / 1.) CH₂Cl₂, ca. -50 deg C, 15 min, 2.) ca. -50 deg C to 20 deg C

2: diethyl ether / -70 °C

3: 81 percent / Ph₃P, DEAD / benzene / 2 h / 20 °C

With oxalyl dichloride; dimethyl sulfoxide; triethylamine; triphenylphosphine; diethylazodicarboxylate; In diethyl ether; benzene;
DOI:10.1021/jo00106a035