Ph₂PC₆H₄CH=N-2-MeOC₆H₄

Base Information

• Chemical Name: Ph₂PC₆H₄CH=N-2-MeOC₆H₄
• CAS No.: 540772-29-0
• Molecular Formula: C₂₆H₂₂NOP
• Molecular Weight: 395.441
• Mol file: 540772-29-0.mol

Synonyms:Ph₂PC₆H₄CH=N-2-MeOC₆H₄

Chemical Property of Ph₂PC₆H₄CH=N-2-MeOC₆H₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ph₂PC₆H₄CH=N-2-MeOC₆H₄

There total 1 articles about Ph₂PC₆H₄CH=N-2-MeOC₆H₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(2-formylphenyl)(diphenyl)phosphine (50777-76-9) + 2-methoxy-phenylamine (90-04-0) → Ph2PC6H4CH=N-2-MeOC6H4 (540772-29-0)

Guidance literature:

In methanol; dichloromethane; at 20 ℃;

DOI:10.1039/b206119h

Reference yield: 94.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + Ph2PC6H4CH=N-2-MeOC6H4 (540772-29-0) → PdCl2P(C6H5)2((C6H4)CHN(C6H4OCH3)) (1209495-71-5)

Guidance literature:

In dichloromethane; soln. of diphenyl(2-(2-methoxyphenyliminomethyl)phenyl)phosphane (3.90 mol) in CH2Cl2 added to soln. of PdCl2(1,5-COD) (3.82 mol) in CH2Cl2; mixt. stirred at room temp. for 2 h; concd. (vac.); pptd. with Et2O; filtered off; washed (Et2O); dried (vac.); elem. anal.;

DOI:10.1002/ejic.200801196

Reference yield: 93.0%

chloromethyl(1,5-cyclooctadiene)palladium(II) + Ph2PC6H4CH=N-2-MeOC6H4 (540772-29-0) → PdCl(CH3)P(C6H5)2((C6H4)CHN(C6H4OCH3)) (1209495-74-8)

Guidance literature:

In dichloromethane; soln. of diphenyl(2-(2-methoxyphenyliminomethyl)phenyl)phosphane (3.87 mol) in CH2Cl2 added to soln. of PdClMe(1,5-COD) (3.84 mol) in CH2Cl2; mixt. stirred at room temp. for 5 d; concd. (vac.); pptd. with hexane; filtered off; washed (hexane); dried (vac.); elem. anal.;

DOI:10.1002/ejic.200801196

upstream raw materials:

(2-formylphenyl)(diphenyl)phosphine

2-methoxy-phenylamine

Downstream raw materials:

trans-[RuCl2(κ2-P,N-2-Ph2PC6H4CHN-2'-C6H4OMe)(PPh3)]

[RhI(CO)(Ph₂PC₆H₄CH=N-2-MeOC₆H₄)]

(RuCl((C₆H₅)2PC₆H₄CHNC₆H₄OCH₃)(P(C₆H₅)3))⁽¹⁺⁾*B(C₆H₅)4^(1-)=(RuCl((C₆H₅)2PC₆H₄CHNC₆H₄OCH₃)(P(C₆H₅)3))(B(C₆H₅)4)

PdCl₂P(C₆H₅)2((C₆H₄)CHN(C₆H₄OCH₃))