[3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

Base Information

Chemical Name:[3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one
CAS No.:164106-86-9
Molecular Formula:C₂₆H₂₄O₉S
Molecular Weight:512.537
Hs Code.:

[3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

Synonyms:[3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

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Chemical Property of [3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

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Technology Process of [3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

There total 1 articles about [3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 108-98-5
thiophenol

: 163981-05-3
(3'aR,7'S,7'aR)-N,N-diethyl-7'-(acetyloxy)-3'a,4',7',7'a-tetrahydro-7-methoxy-2',2'-dimethyl-4'-oxo[5,5'-bi-1,3-benzodioxole]-6-carboxamide

: [3aR-(3aα,11β,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

: 164106-86-9
[3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

Guidance literature:: With triethylamine; In tetrahydrofuran; for 15h; Heating;
DOI:10.1021/jo049153l

Reference yield:

: 164106-86-9
[3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

: (1R,2R,3S,4R)-2,3,4-Trihydroxy-7-methoxy-1-phenylsulfanyl-1,2,3,4-tetrahydro-5,8,10-trioxa-cyclopenta[b]phenanthren-6-one

Guidance literature:: With trifluoroacetic acid; In tetrahydrofuran; water; for 2h; Heating;
DOI:10.1021/jo049153l

Reference yield:

: 164106-86-9
[3aR-(3aα,11α,12β,12aα)]-12-(acetyloxy)-3a,11,12,12a-tetrahydro-6-methoxy-2,2-dimethyl-11-(phenylthio)-5H-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-h][1]benzopyran-5-one

: 783334-61-2
[1R-(1β,2α,3β,4β)]-6-methoxy2,3,4-tri(methoxymethyl)-1,2,3,4-tetrahydro-1-(phenylthio)-2H-[1,3]benzodioxolo[5,6-c]-[1]benzopyran-6-one

Guidance literature:: Multi-step reaction with 2 steps

1: TFA / tetrahydrofuran; H₂O / 2 h / Heating

2: 413 mg / diisopropylethylamine / CH₂Cl₂ / 2 h / Heating

With N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo049153l