C₄₇H₅₉ClO₁₃Si

Base Information

Chemical Name:C₄₇H₅₉ClO₁₃Si
CAS No.:1332271-33-6
Molecular Formula:C₄₇H₅₉ClO₁₃Si
Molecular Weight:895.516
Hs Code.:

C<sub>47</sub>H<sub>59</sub>ClO<sub>13</sub>Si

Synonyms:C₄₇H₅₉ClO₁₃Si

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Chemical Property of C₄₇H₅₉ClO₁₃Si

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Technology Process of C₄₇H₅₉ClO₁₃Si

There total 24 articles about C₄₇H₅₉ClO₁₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1332271-54-1
C₁₉H₂₂O₆

: 1332271-05-2
C₂₈H₃₉ClO₈Si

: 1332271-33-6
C₄₇H₅₉ClO₁₃Si

Guidance literature:: With dmap; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; triethylamine; In dichloromethane; at 0 ℃; for 3h; Inert atmosphere;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-63-2
C₃₁H₄₃ClO₇Si

: 1332271-33-6
C₄₇H₅₉ClO₁₃Si

Guidance literature:: Multi-step reaction with 12 steps

1.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 40 h / 20 °C / Inert atmosphere

2.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 1.17 h / -78 °C / Inert atmosphere

2.2: 0.5 h / -78 °C / Inert atmosphere

3.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

4.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

5.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

6.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

7.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

7.2: Inert atmosphere

8.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

9.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

10.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

11.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

12.1: dmap; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; triethylamine / dichloromethane / 3 h / 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; chromium dichloride; dmap; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; potassium hexamethylsilazane; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; 5.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-26-7
C₃₈H₅₆ClF₃O₁₀SSi₂

: 1332271-33-6
C₄₇H₅₉ClO₁₃Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

2.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

3.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

4.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

5.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

5.2: Inert atmosphere

6.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

7.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

8.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

9.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

10.1: dmap; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; triethylamine / dichloromethane / 3 h / 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; chromium dichloride; dmap; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; pyridinium p-toluenesulfonate; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; acetone; tert-butyl alcohol; 3.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094