D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

Base Information

Chemical Name:D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol
CAS No.:95058-12-1
Molecular Formula:C₁₇H₃₀N₂O₆
Molecular Weight:358.435
Hs Code.:

Synonyms:D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

Suppliers and Price of D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

There total 13 articles about D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 95058-11-0
D,L-(1r,2c,4c,5t,6t)-2-amino-1-O,2-N-carbonyl-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

: 95058-12-1
D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

Guidance literature:: With barium dihydroxide; In 1,4-dioxane; water; at 55 - 60 ℃; for 7h;
DOI:10.1246/cl.1984.1665

Reference yield:

: ((1R,2R,3R,4R,6S)-4-Amino-2,3,6-trihydroxy-cyclohexyl)-carbamic acid benzyl ester

: 95058-12-1
D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

Guidance literature:: Multi-step reaction with 4 steps

1: 74 percent / TsOH / dimethylformamide

2: hydrogen / 10percent Pd/C

3: Et₃N / H₂O; methanol / 3.5 h / Ambient temperature

4: 47 percent / Ba(OH)2*8H₂O / dioxane; H₂O / 7 h / 55 - 60 °C

With barium dihydroxide; hydrogen; toluene-4-sulfonic acid; triethylamine; palladium on activated charcoal; In 1,4-dioxane; methanol; water; N,N-dimethyl-formamide;
DOI:10.1246/cl.1984.1665

Reference yield:

: 95058-09-6
D,L-(1r,2c,4c,5t,6t)-2-amino-5-benzyloxycarbonylamino-1-O,2-N-carbonyl-1,4,6-cyclohexanetriol

: 95058-12-1
D,L-(1r,2c,4c,5t,6t)-2-amino-5-formamido-4,6-bis-O-tetrahydropyranyl-1,4,6-cyclohexanetriol

Guidance literature:: Multi-step reaction with 5 steps

1: Ba(OH)2 / H₂O; dioxane

2: 74 percent / TsOH / dimethylformamide

3: hydrogen / 10percent Pd/C

4: Et₃N / H₂O; methanol / 3.5 h / Ambient temperature

5: 47 percent / Ba(OH)2*8H₂O / dioxane; H₂O / 7 h / 55 - 60 °C

With barium dihydroxide; hydrogen; toluene-4-sulfonic acid; triethylamine; palladium on activated charcoal; In 1,4-dioxane; methanol; water; N,N-dimethyl-formamide;
DOI:10.1246/cl.1984.1665