(S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one

Base Information

Chemical Name:(S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one
CAS No.:1373037-81-0
Molecular Formula:C₂₂H₃₁NO₃
Molecular Weight:357.493
Hs Code.:

Synonyms:(S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one

Chemical Property:

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Technology Process of (S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one

There total 8 articles about (S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77732-35-5
(+)-citronelloyl chloride

: 168297-85-6,352438-06-3
(S)-4-benzyl-5,5-dimethyloxazolidin-2-one

: 1373037-81-0
(S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one

Guidance literature:: (S)-4-benzyl-5,5-dimethyloxazolidin-2-one; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

(+)-citronelloyl chloride; In tetrahydrofuran; hexane; at -78 ℃; for 2h; Inert atmosphere;
DOI:10.1021/ja302552e

Reference yield:

: 1373038-24-4
C₂₁H₂₄F₇NO₃

: 1373037-81-0
(S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h / -78 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.2: 2 h / -78 °C / Inert atmosphere

With lithium aluminium tetrahydride; n-butyllithium; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/ja302552e

Reference yield:

: 1373037-72-9
(S)-4-benzyl-3-(2-cyclohexylacetyl)-5,5-dimethyloxazolidin-2-one

: 1373037-81-0
(S)-4-benzyl-3-((R)-3,7-dimethyloct-6-enoyl)-5,5-dimethyloxazolidin-2-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: tris(triphenylphosphine)ruthenium(II) chloride; zirconium(IV) chloride; triethylamine / dichloromethane / 0.08 h / -78 - 24 °C / Inert atmosphere

1.2: 17 h / -78 - 45 °C / Inert atmosphere

2.1: lithium hydroxide monohydrate; dihydrogen peroxide / tetrahydrofuran; water / 6 h / 0 - 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

3.2: 2 h / -78 °C / Inert atmosphere

With tris(triphenylphosphine)ruthenium(II) chloride; n-butyllithium; lithium hydroxide monohydrate; dihydrogen peroxide; zirconium(IV) chloride; triethylamine; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1021/ja302552e