bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)

Base Information

Chemical Name:bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)
CAS No.:74735-25-4
Molecular Formula:C₄₀H₃₄NiO₂P₂S₂
Molecular Weight:731.478
Hs Code.:

Synonyms:bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)

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Chemical Property of bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)

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Technology Process of bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)

There total 3 articles about bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 98-91-9
thiobenzoic acid

: 14647-23-5
1,2-bis(diphenylphosphino)ethane nickel(II) chloride

: 74735-25-4
bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)

Guidance literature:: thiobenzoic acid; With sodium hydroxide; In methanol; Cooling with ice;

1,2-bis(diphenylphosphino)ethane nickel(II) chloride; In methanol; chloroform; for 4h;
DOI:10.1016/j.ica.2013.11.037

Reference yield:

: 29863-34-1
[Ni(monothiobenzoate)2(C₂H₅OH)0.5]2

: 74735-25-4
bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)

Guidance literature:: With Ph₂PCH₂CH₂PPh₂; In ethanol; N2-atmosphere; molar ratio Ni-complex:dppe=2:1, gentle warming and stirring (1 h); concn. (pptn.; addn. of light petroleum to induce pptn. when necessary),filtration, washing (light petroleum), drying (40°C, vac.); elem . anal.;
DOI:10.1016/S0020-1693(00)88425-X

Reference yield:

: 29863-34-1
Ni₂tetrakis(monothiobebzoato-S)(C₂H₅OH)

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 74735-25-4
bis(monothiobenzoato-S){ethylenebis(diphenylphosphino)}nickel(II)

Guidance literature:: In ethanol; dichloromethane; Ni-complex was dissolved in EtOH and diphos in dichloromethane was added to the soln., the mixt. was left without disturbance; sepd. out;