Technology Process of C16H17BrO4
There total 3 articles about C16H17BrO4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C15H17BrO4; eschenmoser's salt;
With
trimethylsilyl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine;
In
dichloromethane;
at -5 ℃;
for 0.0833333h;
Inert atmosphere;
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 1h;
chemoselective reaction;
DOI:10.3987/COM-12-S(N)91
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: pyridinium hydrobromide perbromide / acetonitrile / 15 h / 20 °C / Inert atmosphere
2.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 2.5 h / 0 - 60 °C / Inert atmosphere
3.1: trimethylsilyl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine / dichloromethane / 0.08 h / -5 °C / Inert atmosphere
3.2: 1 h / 20 °C
With
trimethylsilyl trifluoromethanesulfonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; pyridinium hydrobromide perbromide; N-ethyl-N,N-diisopropylamine;
In
dichloromethane; acetonitrile;
DOI:10.3987/COM-12-S(N)91
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 2.5 h / 0 - 60 °C / Inert atmosphere
2.1: trimethylsilyl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine / dichloromethane / 0.08 h / -5 °C / Inert atmosphere
2.2: 1 h / 20 °C
With
trimethylsilyl trifluoromethanesulfonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; N-ethyl-N,N-diisopropylamine;
In
dichloromethane; acetonitrile;
DOI:10.3987/COM-12-S(N)91
