C₄₁H₅₀O₇

Base Information

• Chemical Name: C₄₁H₅₀O₇
• CAS No.: 403704-43-8
• Molecular Formula: C₄₁H₅₀O₇
• Molecular Weight: 654.844
• Mol file: 403704-43-8.mol

Synonyms:C₄₁H₅₀O₇

Chemical Property of C₄₁H₅₀O₇

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₁H₅₀O₇

There total 6 articles about C₄₁H₅₀O₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C43H52O8 (403704-42-7) → C41H50O7 (403704-43-8)

Guidance literature:

With potassium carbonate; In methanol; water; at 25 ℃; for 5h;

DOI:10.1021/ol016572l

Reference yield:

Benzoic acid (2S,4aS,4bS,6S,6aR,6bR,7S,8R,9aS,10bR,12aS)-2-acetoxy-4a,6a,7-trimethyl-8-(3-methyl-but-3-enyl)-2,3,4,4a,4b,5,6,6a,6b,7,8,9a,10b,11,12,12a-hexadecahydro-1H-9-oxa-pentaleno[2,1-a]phenanthren-6-yl ester (403704-37-0) → C41H50O7 (403704-43-8)

Guidance literature:

Multi-step reaction with 6 steps

1: 96 percent / OsO₄; K₃Fe(CN)6; K₂CO₃ / (DHQ)2PHAL / 2-methyl-propan-2-ol; H₂O / 8 h / 0 °C

2: 97 percent / imidazole; 4-(dimethylamino)pyridine / dimethylformamide / 1.5 h / 25 °C

3: 87 percent / MgBr₂*OEt₂; triethylamine / CH₂Cl₂ / 18 h / 25 °C

4: 96 percent / BF₃*OEt₂ / CH₂Cl₂ / 0.08 h / 0 °C

5: PhI(OAc)2; iodine / cyclohexane; CH₂Cl₂ / 8 h / 0 °C

6: 100 percent / potassium carbonate / methanol; H₂O / 5 h / 25 °C

With 1H-imidazole; dmap; osmium(VIII) oxide; [bis(acetoxy)iodo]benzene; boron trifluoride diethyl etherate; iodine; potassium carbonate; triethylamine; magnesium bromide; potassium hexacyanoferrate(III); Hydroquinone 1,4-phthalazinediyl diether; In methanol; dichloromethane; cyclohexane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 5: Suarez iodine(III) oxidation;

DOI:10.1021/ol016572l

Reference yield:

Benzoic acid (2S,4aS,4bS,6S,6aR,6bR,7S,8R,9aS,10bR,12aS)-2-acetoxy-8-(3,4-dihydroxy-3-methyl-butyl)-4a,6a,7-trimethyl-2,3,4,4a,4b,5,6,6a,6b,7,8,9a,10b,11,12,12a-hexadecahydro-1H-9-oxa-pentaleno[2,1-a]phenanthren-6-yl ester (404574-46-5) → C41H50O7 (403704-43-8)

Guidance literature:

Multi-step reaction with 5 steps

1: 97 percent / imidazole; 4-(dimethylamino)pyridine / dimethylformamide / 1.5 h / 25 °C

2: 87 percent / MgBr₂*OEt₂; triethylamine / CH₂Cl₂ / 18 h / 25 °C

3: 96 percent / BF₃*OEt₂ / CH₂Cl₂ / 0.08 h / 0 °C

4: PhI(OAc)2; iodine / cyclohexane; CH₂Cl₂ / 8 h / 0 °C

5: 100 percent / potassium carbonate / methanol; H₂O / 5 h / 25 °C

With 1H-imidazole; dmap; [bis(acetoxy)iodo]benzene; boron trifluoride diethyl etherate; iodine; potassium carbonate; triethylamine; magnesium bromide; In methanol; dichloromethane; cyclohexane; water; N,N-dimethyl-formamide; 4: Suarez iodine(III) oxidation;

DOI:10.1021/ol016572l

upstream raw materials:

C₄₃H₅₂O₈

Benzoic acid (2S,4aS,4bS,6S,6aR,6bR,7S,8R,9aS,10bR,12aS)-2-acetoxy-4a,6a,7-trimethyl-8-(3-methyl-but-3-enyl)-2,3,4,4a,4b,5,6,6a,6b,7,8,9a,10b,11,12,12a-hexadecahydro-1H-9-oxa-pentaleno[2,1-a]phenanthren-6-yl ester

Benzoic acid (2S,4aS,4bS,6S,6aR,6bR,7S,8R,9aS,10bR,12aS)-2-acetoxy-8-(3,4-dihydroxy-3-methyl-butyl)-4a,6a,7-trimethyl-2,3,4,4a,4b,5,6,6a,6b,7,8,9a,10b,11,12,12a-hexadecahydro-1H-9-oxa-pentaleno[2,1-a]phenanthren-6-yl ester

C₄₃H₅₄O₈

Downstream raw materials:

C₄₁H₄₈O₇

C₄₁H₄₇N₃O₇

C₄₁H₄₇BrO₇