C₃₅H₅₃NSO₈

Base Information

• Chemical Name: C₃₅H₅₃NSO₈
• CAS No.: 1004311-49-2
• Molecular Formula: C₃₅H₅₃NO₈S
• Molecular Weight: 647.874
• Mol file: 1004311-49-2.mol

Synonyms:C₃₅H₅₃NSO₈

Chemical Property of C₃₅H₅₃NSO₈

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₅H₅₃NSO₈

There total 11 articles about C₃₅H₅₃NSO₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

C28H47NO6 (1004311-48-1) + p-toluenesulfonyl chloride (98-59-9) → C35H53NSO8 (1004311-49-2)

Guidance literature:

With triethylamine; In dichloromethane; at 5 ℃; for 72h;

DOI:10.1055/s-2007-991056

Reference yield:

1,2-epoxytetradecane (3234-28-4) → C35H53NSO8 (1004311-49-2)

Guidance literature:

Multi-step reaction with 11 steps

1.1: 41 percent / H₂O / (R,R)-Co(III)(salen)*OAc / 24 h / 0 °C

2.1: 94 percent / CuI / tetrahydrofuran / 12 h / -78 °C

3.1: Et₃N / CH₂Cl₂ / 2 h

4.1: NaN₃ / dimethylformamide / 45 °C

5.1: PPh₃ / tetrahydrofuran; H₂O / 12 h / 20 °C

6.1: Na₂CO₃ / dioxane; H₂O / 0 - 20 °C

7.1: BH₃*SMe₂ / tetrahydrofuran / 3 h / 0 - 20 °C

7.2: 87 percent / NaOH; H₂O₂ / 6 h / 0 - 20 °C

8.1: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 1 h / -78 - -60 °C

9.1: tetrahydrofuran / 24 h / 20 °C

10.1: 97 percent / (DHQD)2PHAL; osmium tetroxide; MeSO₂NH₂ / K₂CO₃; potassium ferricyanide / 2-methyl-propan-2-ol; H₂O / 24 h / 0 °C

11.1: 88 percent / Et₃N / CH₂Cl₂ / 72 h / 5 °C

With copper(l) iodide; osmium(VIII) oxide; sodium azide; oxalyl dichloride; methanesulfonamide; dimethylsulfide borane complex; water; sodium carbonate; dimethyl sulfoxide; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; triphenylphosphine; potassium carbonate; potassium hexacyanoferrate(III); In tetrahydrofuran; 1,4-dioxane; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 1.1: Jacobsen's hydrolytic kinetic resolution / 5.1: Staudinger reaction / 8.1: Swern oxidation / 9.1: Wittig reaction / 10.1: Sharpless asymmetric dihydroxylation;

DOI:10.1055/s-2007-991056

Reference yield:

C17H34SO3 → C35H53NSO8 (1004311-49-2)

Guidance literature:

Multi-step reaction with 8 steps

1.1: NaN₃ / dimethylformamide / 45 °C

2.1: PPh₃ / tetrahydrofuran; H₂O / 12 h / 20 °C

3.1: Na₂CO₃ / dioxane; H₂O / 0 - 20 °C

4.1: BH₃*SMe₂ / tetrahydrofuran / 3 h / 0 - 20 °C

4.2: 87 percent / NaOH; H₂O₂ / 6 h / 0 - 20 °C

5.1: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 1 h / -78 - -60 °C

6.1: tetrahydrofuran / 24 h / 20 °C

7.1: 97 percent / (DHQD)2PHAL; osmium tetroxide; MeSO₂NH₂ / K₂CO₃; potassium ferricyanide / 2-methyl-propan-2-ol; H₂O / 24 h / 0 °C

8.1: 88 percent / Et₃N / CH₂Cl₂ / 72 h / 5 °C

With osmium(VIII) oxide; sodium azide; oxalyl dichloride; methanesulfonamide; dimethylsulfide borane complex; sodium carbonate; dimethyl sulfoxide; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; triphenylphosphine; potassium carbonate; potassium hexacyanoferrate(III); In tetrahydrofuran; 1,4-dioxane; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 2.1: Staudinger reaction / 5.1: Swern oxidation / 6.1: Wittig reaction / 7.1: Sharpless asymmetric dihydroxylation;

DOI:10.1055/s-2007-991056

upstream raw materials:

C₂₈H₄₇NO₆

p-toluenesulfonyl chloride

1,2-epoxytetradecane

C₂₈H₄₅NO₄