1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide

Base Information

• Chemical Name: 1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide
• CAS No.: 1338787-76-0
• Molecular Formula: C₂₇H₂₈N₃OS₂*I
• Molecular Weight: 601.575
• Mol file: 1338787-76-0.mol

Synonyms:1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide

Chemical Property of 1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide

There total 1 articles about 1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

C21H20N2S2 (1258875-49-8) + 2-(chloromethyl)-4,5-dimethyl-1,3-oxazole (141118-71-0) → 1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide (1338787-76-0)

Guidance literature:

With sodium iodide; In acetone; at 50 ℃; for 40h; Inert atmosphere;

DOI:10.1039/c1nj20161a

Reference yield: 68.0%

dichloro(mesitylene)ruthenium(II) dimer + 1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-1H-imidazolium iodide (1338787-76-0) → [(η6-mesitylene)Ru(1-((4,5-dimethyloxazol-2-yl)methyl)-4,5-bis(2,5-dimethylthiophen-3-yl)-3-phenyl-imidazoline-2-ylidene)Cl]PF6

Guidance literature:

With silver(I) oxide; In dichloromethane; mixt. Ag2O and imidazolium iodide in CH2Cl2 was stirred in the dark for 3-4 h, Ru complex was added, stirred for 4 h in the dark; soln. was filtered through Celite and evapd. in vacuo, MeOH was added, after standing for 1 h, soln. was filtered through Celite, NH4PF6 was added, solvent was removed in vacuo, chromy. on alumina followed by recrystn. from MeOH-Et2O;elem. anal.;

DOI:10.1039/c1nj20161a

upstream raw materials:

C₂₁H₂₀N₂S₂

2-(chloromethyl)-4,5-dimethyl-1,3-oxazole