Tetrakis(4-methoxyphenyl)ethylene

Base Information

• Chemical Name: Tetrakis(4-methoxyphenyl)ethylene
• CAS No.: 10019-24-6
• Molecular Formula: C30H28 O4
• Molecular Weight: 452.55
• Hs Code.: 2909309090
• NSC Number: 132124
• DSSTox Substance ID: DTXSID00142999
• Nikkaji Number: J2.291H
• Wikidata: Q83006637
• Mol file: 10019-24-6.mol

Synonyms:tetrakis(4-methoxyphenyl)ethylene;tetrakis(p-methoxyphenyl)ethylene

Chemical Property of Tetrakis(4-methoxyphenyl)ethylene

Chemical Property:

• Melting Point: 183 °C
• Boiling Point: 574.1±45.0 °C(Predicted)
• Flash Point: 123.1oC
• PSA: 36.92000
• Density: 1.126±0.06 g/cm3(Predicted)
• LogP: 6.72840
• XLogP3: 7.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 452.19875937
• Heavy Atom Count: 34
• Complexity: 508

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1,2,2-Tetrakis(4-methoxyphenyl)ethene 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C(=C(C2=CC=C(C=C2)OC)C3=CC=C(C=C3)OC)C4=CC=C(C=C4)OC

Technology Process of Tetrakis(4-methoxyphenyl)ethylene

There total 54 articles about Tetrakis(4-methoxyphenyl)ethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triphenylphosphorane (153785-57-0) → 1,1,2,2-tetrakis(4-methoxyphenyl)ethene (10019-24-6)

Guidance literature:

With woollins’ reagent; In toluene; for 1h; Heating;

DOI:10.1039/b702818k

Reference yield: 99.0%

bis(p-methoxyphenyl)methanone (90-96-0) → 1,1,2,2-tetrakis(4-methoxyphenyl)ethene (10019-24-6)

Guidance literature:

With woollins’ reagent; In toluene; for 20h; Heating;

DOI:10.1039/b702818k

Reference yield: 98.0%

1,1,2,2-tetrakis(4-methoxyphenyl)ethene (10019-24-6) → tetraanisylethylene cation-radical (10019-24-6)

Guidance literature:

With methanesulfonic acid; chloranil; In dichloromethane; at 25 ℃; for 0.333333h;

DOI:10.3891/acta.chem.scand.52-0114

upstream raw materials:

thioformaldehyde

Bis(p-methoxyphenyl)diazomethan

dichloro-bis-(4-methoxy-phenyl)-methane

2-acetoxy-1,1,1,2-tetrakis-(4-methoxy-phenyl)-ethane

Downstream raw materials:

1,1,2,2-tetrakis(4-methoxyphenyl)ethane

3,6-dimethoxy-9,10-bis(4-methoxyphenyl)phenanthrene

tetrakis-(4-methoxy-phenyl)-ethanone

bis(p-methoxyphenyl)methanone

Refernces

• 1、 Donnier-Maréchal, Marion,Abdullayev, Shuay,Bauduin, Marvin,Pascal, Yoann,Fu, Meng-Qi,He, Xiao-Peng,Gillon, Emilie,Imberty, Anne,Kipnis, Eric,Dessein, Rodrigue,Vidal, Sébastien. "Tetraphenylethylene-based glycoclusters with aggregation-induced emission (AIE) properties as high-affinity ligands of bacterial lectins". . p. 8804 - 8809. Retrieved 2018.
• 2、 Coffey,C.E.. "-". . p. 1623 - 1626. Retrieved 1961.
• 3、 Alper,Paik. "-". . p. 3522. Retrieved 1977.
• 4、 Zhao, Qian,Chen, Yong,Li, Sheng-Hua,Liu, Yu. "Tunable white-light emission by supramolecular self-sorting in highly swollen hydrogels". . p. 200 - 203. Retrieved 2017.
• 5、 Tanabe et al.. "". . p. 1545. Retrieved 1978.
• 6、 Xu, Pengfei,Bao,Yu, Chenyi,Qiu, Qianqian,Wei, Mengru,Xi, Wenbin,Qian, Zhaosheng,Feng, Hui. "A water-soluble molecular probe with aggregation-induced emission for discriminative detection of Al3+ and Pb2+ and imaging in seedling root of Arabidopsis". . . Retrieved 2019.
• 7、 Zeng, Yu-Ting,Gao, Si-Yu,Traskovskis, Kaspars,Gao, Baoxiang,Ren, Xiang-Kui. "Polyhedral oligosilsesquioxane tethered tetraphenylethylene as turn-on fluorescent sensor for fluoride ions detection". . . Retrieved 2021.
• 8、 -. "Development of multifunctional optical material based on tetrastyrene structure and preparation method thereof". Paragraph 0043-0045; 0056-0058. . Retrieved 2022/04/06.