3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate

Base Information

Chemical Name:3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate
CAS No.:115130-55-7
Molecular Formula:C₃₉H₄₀Cl₃NO₁₀
Molecular Weight:789.106
Hs Code.:

Synonyms:3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate

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Chemical Property of 3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate

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Technology Process of 3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate

There total 4 articles about 3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 88988-46-9
2-O-acetyl-3,4,6-tetra-O-benzyl-α-D-glucopyranose

: 115130-55-7
3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / anhydrous NH₃ / methanol / 0 deg C_.,4 h then room t., 12 h

2: 1) 2-methylpyridine, 2) hydrazine acetate / 1) toluene, dichloromethene, 0 deg C_., 2 h; 2) N,N-dimethylformamide, 55 deg C, 4 h, room temp., 2 h

3: 1) K₂CO₃, 2) NaH / 1) dichloromethane, room temp., 19 h; 2) CH₂Cl₂, 3 h

With α-picoline; ammonia; hydrazinium monoacetate; sodium hydride; potassium carbonate; In methanol;
DOI:10.1016/S0008-6215(00)90879-6

Reference yield:

: 20672-66-6,40246-26-2,84926-76-1,114179-79-2,115184-49-1
3,4,6-tri-O-benzyl-D-glucopyranose

: 115130-55-7
3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) 2-methylpyridine, 2) hydrazine acetate / 1) toluene, dichloromethene, 0 deg C_., 2 h; 2) N,N-dimethylformamide, 55 deg C, 4 h, room temp., 2 h

2: 1) K₂CO₃, 2) NaH / 1) dichloromethane, room temp., 19 h; 2) CH₂Cl₂, 3 h

With α-picoline; hydrazinium monoacetate; sodium hydride; potassium carbonate;
DOI:10.1016/S0008-6215(00)90879-6

Reference yield:

: 4521-61-3
3,4,5-Trimethoxybenzoyl chloride

: 115130-55-7
3,4,6-tri-O-benzyl-2-O-(3,4,5-trimethoxybenzoyl)-α-D-glucopyranosyl trichloroacetamidate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) 2-methylpyridine, 2) hydrazine acetate / 1) toluene, dichloromethene, 0 deg C_., 2 h; 2) N,N-dimethylformamide, 55 deg C, 4 h, room temp., 2 h

2: 1) K₂CO₃, 2) NaH / 1) dichloromethane, room temp., 19 h; 2) CH₂Cl₂, 3 h

With α-picoline; hydrazinium monoacetate; sodium hydride; potassium carbonate;
DOI:10.1016/S0008-6215(00)90879-6