[Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF₃SO₃)](CF₃SO₃)

Base Information

• Chemical Name: [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF₃SO₃)](CF₃SO₃)
• CAS No.: 1073530-42-3
• Molecular Formula: CF₃O₃S*C₅₂H₃₆F₃N₄O₈P₂Re₂S
• Molecular Weight: 1517.37

Synonyms:[Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF₃SO₃)](CF₃SO₃)

Chemical Property of [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF₃SO₃)](CF₃SO₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF₃SO₃)](CF₃SO₃)

There total 1 articles about [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF₃SO₃)](CF₃SO₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

[Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)3](CF3SO3)2 → [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF3SO3)](CF3SO3) (1073530-42-3)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); soln. Re complex in THF was irradiated with high-pressure mercury lamp with uranium glass filter for 25 min; soln. was concd. in vacuo, Et2O was added, ppt. was filtered, washed with Et2O and dried in vacuo;

DOI:10.1021/ja8044579

Reference yield: 90.0%

[Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF3SO3)](CF3SO3) (1073530-42-3) + bis(diphenylphosphino)acetylene (5112-95-8) → [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(η1-bis(diphenylphosphino)acetylene)](CF3SO3)2

Guidance literature:

In dichloromethane; soln. Re complex and ligand in CH2Cl2 was heated at 40°C for 1 day in dim light; soln. was concd., Et2O was added, ppt. was filtered, washed with Et2O and dried in vacuo;

DOI:10.1021/ja8044579

Reference yield: 72.0%

ammonium hexafluorophosphate + [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF3SO3)](CF3SO3) (1073530-42-3) + bis(diphenylphosphino)acetylene (5112-95-8) → [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)ecetylene)(Re(2,2'-bipyridine)(CO)2(bis(diphenylphosphino)acetylene))2Re(2,2'-bipyridine)(CO)3](PF6)4

Guidance literature:

In dichloromethane; soln. Re complex and 0.5 equiv. ligand in CH2Cl2 was stirred at room temp. for 1 day and at 40°C for 1 day in dim light; soln. was evapd., size exclusion chromy., to soln. Re complex in MeOH soln. NH4PF6 in MeOH was added, ppt. was filtered, washed with Et2O and dried in vacuo; elem. anal.;

DOI:10.1021/ja8044579

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1073530-42-3 [Re(2,2'-bipyridine)(CO)3(bis(diphenylphosphino)acetylene)Re(2,2'-bipyridine)(CO)2(CF₃SO₃)](CF₃SO₃)

Send

Send

Metric Ton KG G Pound L ML

Send

Send