Chromium(1+), bis(h6-benzene)-, iodide (1:1)

Base Information

• Chemical Name: Chromium(1+), bis(h6-benzene)-, iodide (1:1)
• CAS No.: 12089-29-1
• Molecular Formula: C₁₂H₁₂Cr*I
• Molecular Weight: 335.128
• Mol file: 12089-29-1.mol

Synonyms:Bis(benzene)chromiumiodide (6CI,7CI); Chromium(1+), bis(benzene)-, iodide (8CI); Chromium(1+), bis(h6-benzene)-, iodide (9CI);Benzene, chromium complex; Bis(benzene)chromium(1+) iodide; Chromium,bis(benzene)iodo-; Dibenzenechromium iodide

Chemical Property of Chromium(1+), bis(h6-benzene)-, iodide (1:1)

Chemical Property:

• PSA: 0.00000
• LogP: 0.37720

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: Poison by intravenous route. When heated to decomposition it emits toxic fumes of Cr and I−.:;"> −." target="_blank">Poison by intravenous route. When heated to decomposition it emits toxic fumes of Cr and I−.:

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chromium(1+), bis(h6-benzene)-, iodide (1:1)

There total 4 articles about Chromium(1+), bis(h6-benzene)-, iodide (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + ((C6F5)3Ge)2HgI(1-)*(C6H6)2Cr(1+)=((C6F5)3Ge)2HgI((C6H6)2Cr) → bis(benzene)chromium(I) iodide (12089-29-1,114737-15-4) + bis{tris(pentafluorophenyl)germyl}mercury (73208-62-5,63699-82-1,59949-20-1)

Guidance literature:

In toluene; a toluene soln. of Pt-complex was added to a soln. of mercurate in toluene, mixt. was kept in a sealed evacuated ampoule at 20°C for 15 h; crystals of (C6H6)2CrI were sepd. (identified by IR, ESR spectral data and melting point), soln. was concd., hexane added to give crystals of HgPt-complex (identified by LSC analysis and IR spectroscopy);

DOI:10.1016/S0022-328X(00)99406-3

Reference yield:

potassium triiodide (12298-68-9,153507-24-5) + bis(benzene)chromium(0) (1271-54-1) → diphenylbenzene chrome iodide (99116-67-3) + bisbiphenylchromium iodide (12099-17-1) + bis(benzene)chromium(I) iodide (12089-29-1,114737-15-4)

Guidance literature:

With aluminium trichloride; air; sulfur dioxide; In ethanol; ammonia; acetic acid; react. of (C6H6)2Cr and AlCl3;decompn. with NH3/ice;oxidn. with air;pptg. with KI3 in acetic acid;adding SO2 in ethanol to the formed mixture;

Reference yield:

potassium triiodide (12298-68-9,153507-24-5) + bis(benzene)chromium(0) (1271-54-1) + bis(η6-diphenyl)chromium(0) (12099-15-9) → diphenylbenzene chrome iodide (99116-67-3) + bisbiphenylchromium iodide (12099-17-1) + bis(benzene)chromium(I) iodide (12089-29-1,114737-15-4)

Guidance literature:

With aluminium trichloride; air; sulfur dioxide; In ethanol; react. at 120 °C;hydrolysis;oxidn. with air;pptg. with KI3;adding SO2/alcohol;

upstream raw materials:

potassium triiodide

bis(benzene)chromium⁽⁰⁾

bis(η6-diphenyl)chromium(0)

tetrakis(triphenylphosphine)platinum

Downstream raw materials:

bis(benzene)chromium⁽⁰⁾

Refernces