Technology Process of 6-<(tert-butyldiphenylsilyl)oxy>-1--2,4,8-tetradecatriene
There total 7 articles about 6-<(tert-butyldiphenylsilyl)oxy>-1--2,4,8-tetradecatriene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
pyridine; hydrogen;
Lindlar's catalyst;
In
hexane;
for 10h;
under 760 Torr;
DOI:10.1021/jo00356a004
- Guidance literature:
-
Multi-step reaction with 7 steps
1: oxalyl chloride, DMF / benzene / Ambient temperature
2: benzene; diethyl ether / -10 - -5 °C
3: Rh(OAc)2 / 1 h / Ambient temperature
4: CeCl3*5H2O, NaBH4 / propan-2-ol; H2O
5: pyridine / 0 °C
6: imidazole / dimethylformamide / Ambient temperature
7: 98 percent / H2, pyridine / Lindlar catalyst / hexane / 10 h / 760 Torr
With
rhodium(II) acetate; pyridine; 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride; oxalyl dichloride; hydrogen; N,N-dimethyl-formamide;
Lindlar's catalyst;
In
diethyl ether; hexane; water; N,N-dimethyl-formamide; isopropyl alcohol; benzene;
DOI:10.1021/jo00356a004
- Guidance literature:
-
Multi-step reaction with 4 steps
1: CeCl3*5H2O, NaBH4 / propan-2-ol; H2O
2: pyridine / 0 °C
3: imidazole / dimethylformamide / Ambient temperature
4: 98 percent / H2, pyridine / Lindlar catalyst / hexane / 10 h / 760 Torr
With
pyridine; 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride; hydrogen;
Lindlar's catalyst;
In
hexane; water; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/jo00356a004
