Mn(CO)2(PMePh2)(η5-CH3C5H4)

Base Information

Chemical Name:Mn(CO)2(PMePh2)(η5-CH3C5H4)
CAS No.:37685-57-7
Molecular Formula:C₂₁H₂₀MnO₂P
Molecular Weight:390.3
Hs Code.:

Synonyms:Mn(CO)2(PMePh2)(η5-CH3C5H4)

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Chemical Property of Mn(CO)2(PMePh2)(η5-CH3C5H4)

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Technology Process of Mn(CO)2(PMePh2)(η5-CH3C5H4)

There total 2 articles about Mn(CO)2(PMePh2)(η5-CH3C5H4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: methylcyclopentadienyl manganese(I) tricarbonyl

: 1486-28-8
diphenyl(methyl)phosphine

: 37685-57-7
Mn(CO)2(PMePh2)(η5-CH3C5H4)

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); a soln. of Mn-complex in THF was cooled to 0°C under Ar and irradiated, ligand was added, soln. was stirred at room temp. to 12 h; THF was removed under vac., solid was redissolved in ether, filtered under Ar, hexane was added, allowed to cool, purified by Florisil chromy. and/or recrystd. under Ar;
DOI:10.1021/ja00325a011

Reference yield:

: (acetonitrile)dicarbonyl(methylcyclopentadienyl)manganese(I)

: 1486-28-8
diphenyl(methyl)phosphine

: 37685-57-7
Mn(CO)2(PMePh2)(η5-CH3C5H4)

Guidance literature:: In acetonitrile; Electrochem. Process; under N2 or Ar, electrocatalysis at 22°C at Pt-gauze electrode (50 μA), supporting electrolyte 0.1 N tetraethylammonium perchlorate;
DOI:10.1016/0022-328X(86)84060-8

Reference yield: 80.0%

: 37685-57-7
Mn(CO)2(PMePh2)(η5-CH3C5H4)

: 69036-00-6
1-chloro-2,2-diphenyl-1-(trimethylsilyl)ethene

: 119747-59-0
CH₃C₅H₄Mn(CO)PCH₃(C₆H₅)2CC(C₆H₅)2

Guidance literature:: In toluene; byproducts: CO, (CH3)3SiCl; Irradiation (UV/VIS); (N2); soln. of Mn complex and vinyl compd. was irradiated at -20°C for 3 h, filtered soln. was evpd. to dryness under high vac.; chromy. (silica gel, petroleum ether/toluene 10:1) at -20°C; elem. anal.;