4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene

Base Information

• Chemical Name: 4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene
• CAS No.: 1141450-82-9
• Molecular Formula: C₃₇H₃₆BF₂IN₄
• Molecular Weight: 712.432
• Mol file: 1141450-82-9.mol

Synonyms:4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene

Chemical Property of 4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene

There total 2 articles about 4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.3%

4-dimethylamino-benzaldehyde (100-10-7) + 4,4-difluoro-8-(4'-iodophenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene → 4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene (1141450-82-9)

Guidance literature:

With piperidine; acetic acid; In N,N-dimethyl-formamide; at 130 ℃; for 0.75h; Microwave irradiation;

Reference yield: 58.0%

4-dimethylamino-benzaldehyde (100-10-7) + 4,4-difluoro-8-(4'-iodophenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene → C28H27BF2IN3 (1253452-02-6,949108-71-8) + 4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene (1141450-82-9)

Guidance literature:

With piperidine; toluene-4-sulfonic acid; In toluene; at 120 ℃; for 24h;

DOI:10.1002/chem.200801911

Reference yield: 99.0%

N,N-Dimethylpropargylamin (7223-38-3) + 4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene (1141450-82-9) → C47H52BIN6

Guidance literature:

N,N-Dimethylpropargylamin; With ethylmagnesium bromide; In tetrahydrofuran; at 60 ℃; for 12h; Schlenk technique; Inert atmosphere;

4,4-difluoro-8-(4-iodolphenyl) 3,5-di(4′-NN-dimethylstyrylphenyl) 1,7-dimethyl-4-bora-3a,4-adiaza-s-indacene; In tetrahydrofuran; at 60 ℃; for 0.25h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.201801540

upstream raw materials:

4-dimethylamino-benzaldehyde

Downstream raw materials:

C₄₆H₄₉BF₂N₄O₂

C₆₆H₅₁BF₂N₄

C₁₀₃H₈₆B₂F₄N₈

C₈₉H₇₆B₂F₄N₆