10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane

Base Information

• Chemical Name: 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane
• CAS No.: 750646-80-1
• Molecular Formula: C₃₂H₃₅BN₂O₃
• Molecular Weight: 506.452
• Mol file: 750646-80-1.mol

Synonyms:10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane

Chemical Property of 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane

There total 2 articles about 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

→ 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane (750646-80-1)

Guidance literature:

Reference yield:

9-BBN triflate (62731-43-5) → 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane (750646-80-1)

Guidance literature:

5-(4-methoxyphenyl)dipyrromethane; With ethylmagnesium bromide; In tetrahydrofuran; at 20 ℃; for 0.166667h;

S-(2-pyridyl) 4-methoxythiobenzoate; In tetrahydrofuran; at -78 ℃; for 0.166667h;

9-BBN triflate; With triethylamine; In dichloromethane; at 20 ℃; for 1h;

Reference yield: 78.0%

10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane (750646-80-1) → 1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane (665005-96-9)

Guidance literature:

With pentan-1-ol; In tetrahydrofuran; for 1 - 1.5h; Product distribution / selectivity; Heating / reflux;

upstream raw materials:

9-BBN triflate

Downstream raw materials:

1-(4-methoxybenzoyl)-5-(4-methoxyphenyl)dipyrromethane

Refernces

• 1、 -. "Boron complexation strategy for use in manipulating 1-acyldipyrromethanes". Page/Page column 8-12; 17; 19. . Retrieved 2008/06/13.