1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene

Base Information

• Chemical Name: 1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene
• CAS No.: 136028-37-0
• Molecular Formula: C₁₄H₁₇ClS
• Molecular Weight: 252.808
• Mol file: 136028-37-0.mol

Synonyms:1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene

Chemical Property of 1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene

There total 1 articles about 1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-methyl-benzaldehyde (104-87-0) + diethyl (4-chloro-1-methylthio-3-pentenyl)phosphonate (136028-33-6,136028-34-7) → 1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene (136028-37-0)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) THF, hexane, -70 deg C, 2 h, 2.) THF, hexane, -70 deg C, 2 h;

DOI:10.1080/00397919108019788

Reference yield: 64.0%

1-((1Z,4Z)-5-Chloro-2-methylsulfanyl-hexa-1,4-dienyl)-4-methyl-benzene (136028-37-0) → 1-(4-methylphenyl)-hexane-2,5-dione (70855-13-9)

Guidance literature:

With titanium tetrachloride; In methanol; dichloromethane; acetone; Ambient temperature;

DOI:10.1080/00397919108019788

upstream raw materials:

4-methyl-benzaldehyde

diethyl (4-chloro-1-methylthio-3-pentenyl)phosphonate

Downstream raw materials:

1-(4-methylphenyl)-hexane-2,5-dione