tetrakis(2,6-dimethyl-4-bromophenyl isocyanide)dipalladium(I) dichloride

Base Information

• Chemical Name: tetrakis(2,6-dimethyl-4-bromophenyl isocyanide)dipalladium(I) dichloride
• CAS No.: 98119-26-7
• Molecular Formula: C₃₆H₃₂Br₄Cl₂N₄Pd₂
• Molecular Weight: 1124.04
• Mol file: 98119-26-7.mol

Synonyms:tetrakis(2,6-dimethyl-4-bromophenyl isocyanide)dipalladium(I) dichloride

Chemical Property of tetrakis(2,6-dimethyl-4-bromophenyl isocyanide)dipalladium(I) dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tetrakis(2,6-dimethyl-4-bromophenyl isocyanide)dipalladium(I) dichloride

There total 2 articles about tetrakis(2,6-dimethyl-4-bromophenyl isocyanide)dipalladium(I) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

dichlorobis(2,6-dimethyl-4-bromophenyl isocyanide)palladium(II) (97775-32-1) → tetrakis(2,6-dimethyl-4-bromophenyl isocyanide)dipalladium(I) dichloride (98119-26-7)

Guidance literature:

With sodium perchlorate; In acetonitrile; Electrolysis; electolysis carried out at -1.5 V vs. SCE in 0.1 M NaClO4-CH3CN soln., ca. 1 F of charge per mole passed, Pt electrode;

DOI:10.1246/bcsj.60.2665

Reference yield:

tris(dibenzylideneacetone)dipalladium(0) * CHCl3 (52522-40-4) + dichlorobis(4-bromo-2,6-xylyl isocyanide)palladium(II) (97775-32-1) + 5-bromo-2-isocyano-1,3-dimethylbenzene (24139-49-9) → dichlorotetrakis(4-bromo-2,6-xylyl isocyanide)dipalladium(I) (98119-26-7)

Guidance literature:

In not given; react. of Pd2(dba)3(CHCl3), isocyanide and dichlorobis(isocyanide)palladium(II) in 1:4:2 ratio;

DOI:10.1246/bcsj.58.1843

upstream raw materials:

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ * CHCl₃

dichlorobis(4-bromo-2,6-xylyl isocyanide)palladium(II)

5-bromo-2-isocyano-1,3-dimethylbenzene

dichlorobis(2,6-dimethyl-4-bromophenyl isocyanide)palladium(II)