(RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride

Base Information

• Chemical Name: (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride
• CAS No.: 253316-04-0
• Molecular Formula: C₁₇H₂₆ClNO₃S
• Molecular Weight: 359.917
• Mol file: 253316-04-0.mol

Synonyms:(RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride

Chemical Property of (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride

There total 2 articles about (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

N-<(4-Nitrophenyl)sulfonyloxy>carbamidsaeuremethylester (55131-07-2) + 2,4,6-triisopropylbenzenesulfinyl chloride (117659-09-3) → (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride (253316-04-0)

Guidance literature:

With triethylamine; In toluene; at 20 ℃;

DOI:10.1080/10426509908037031

Reference yield:

2,4,6-triisopropyl-benzenesulfinic acid (18099-26-8) → (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride (253316-04-0)

Guidance literature:

Multi-step reaction with 2 steps

1: SOCl₂ / 2 h / 25 °C

2: 29 percent / Et₃N / toluene / 20 °C

With thionyl chloride; triethylamine; In toluene; 1: Chlorination / 2: Substitution;

DOI:10.1080/10426509908037031

Reference yield: 96.0%

1H-imidazole (288-32-4) + (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride (253316-04-0) → (RS)-1-[N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl]-imidazole

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 ℃;

DOI:10.1080/10426509908037031

upstream raw materials:

N-<(4-Nitrophenyl)sulfonyloxy>carbamidsaeuremethylester

2,4,6-triisopropylbenzenesulfinyl chloride

2,4,6-triisopropyl-benzenesulfinic acid