(5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

Base Information

Chemical Name:(5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene
CAS No.:165403-05-4
Molecular Formula:C₂₆H₄₈O₃SSi₂
Molecular Weight:496.902
Hs Code.:

Synonyms:(5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

Suppliers and Price of (5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

There total 5 articles about (5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 165403-05-4
(5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / 2,6-lutidine / CH₂Cl₂ / 1.) 0 deg C, 1 h, 2.) RT, 2 h

2: 1.) 9-BBN, 2.) Pd(PPh₃)4 / 1.)a) THF, RT, 30 min, b) reflux, 3 h, 2.) benzene, 110 deg C, 3 h

With 2,6-dimethylpyridine; 9-borabicyclo[3.3.1]nonane dimer; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane;

Reference yield:

: 76513-69-4
(2-trimethylethylsilylethoxy)methyl chloride

: 165403-05-4
(5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / i-Pr₂EtN / CH₂Cl₂ / 1.) 0 deg C, 1 h, 2.) RT, 24 h

2: 1.) sec-BuLi, 2.) (-)-B-methoxydiisopinocampheylborane

3: 96 percent / 2,6-lutidine / CH₂Cl₂ / 1.) 0 deg C, 1 h, 2.) RT, 2 h

4: 1.) 9-BBN, 2.) Pd(PPh₃)4 / 1.)a) THF, RT, 30 min, b) reflux, 3 h, 2.) benzene, 110 deg C, 3 h

With (-)-B-methoxydiisopinocamphenylborane; 2,6-dimethylpyridine; 9-borabicyclo[3.3.1]nonane dimer; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sec.-butyllithium; N-ethyl-N,N-diisopropylamine; In dichloromethane;

Reference yield:

: 161973-89-3
3-<<2-(trimethylsilyl)ethoxy>methoxy>-1-propene

: 165403-05-4
(5R,6R)-6-(tert-butyldimethylsiloxy)-2-(phenylthio)-5-<<2-(trimethylsilyl)ethoxy>methoxy>-1-octene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) sec-BuLi, 2.) (-)-B-methoxydiisopinocampheylborane

2: 96 percent / 2,6-lutidine / CH₂Cl₂ / 1.) 0 deg C, 1 h, 2.) RT, 2 h

3: 1.) 9-BBN, 2.) Pd(PPh₃)4 / 1.)a) THF, RT, 30 min, b) reflux, 3 h, 2.) benzene, 110 deg C, 3 h

With (-)-B-methoxydiisopinocamphenylborane; 2,6-dimethylpyridine; 9-borabicyclo[3.3.1]nonane dimer; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sec.-butyllithium; In dichloromethane;