methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

Base Information

Chemical Name:methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate
CAS No.:113830-50-5
Molecular Formula:C9H12 Br2 O2
Molecular Weight:311.9984
Hs Code.:

Synonyms:Cyclopropanecarboxylicacid, 3-(2,2-dibromoethenyl)-2,2-dimethyl-, methyl ester, cis-;cis-Decamethrinic acid methyl ester

Suppliers and Price of methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

Chemical Property:

Vapor Pressure:0.00591mmHg at 25°C
Boiling Point:272.9°C at 760 mmHg
Flash Point:118.9°C
PSA：26.30000
Density:1.784g/cm³
LogP:3.06280

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

There total 1 articles about methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

: 61775-87-9
methyl <1R,cis>-2,2-dimethyl-3-(2,2-dibromovinyl)cyclopropanecarboxylate

: 61775-88-0,64364-04-1,64364-05-2
(1R,3R)-3-((Z)-2-Bromo-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

: 61775-88-0,64364-04-1,64364-05-2
(1R,3R)-3-((E)-2-Bromo-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

: 53179-78-5,59952-39-5,61914-48-5,63538-10-3,63597-73-9,63949-77-9,72691-16-8,72691-18-0,74560-76-2
3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

: 61775-87-9,64364-00-7,71461-39-7,72345-91-6,113830-50-5,114672-72-9,122566-21-6
(1R,3S)-3-(2,2-Dibromo-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

Guidance literature:: In methanol; Further byproducts given; Irradiation;

Reference yield: 72.0%

: 133472-27-2
4-fluorophenylzinc chloride

: 113830-50-5
methyl cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

: 133472-23-8
methyl cis-3-<(Z)-2-bromo-2-(4-fluorophenyl)ethenyl>-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride; In tetrahydrofuran; Ambient temperature;
DOI:10.1021/jo00012a048

Reference yield: 57.0%

: 81745-84-8
2-thienylzinc chloride

: 113830-50-5
methyl cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

: 133472-24-9
methyl cis-3-<2,2-di(2-thienyl)ethenyl>-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride; In tetrahydrofuran; for 18h; Ambient temperature;
DOI:10.1021/jo00012a048