C₂₇H₃₆OSi

Base Information

Chemical Name:C₂₇H₃₆OSi
CAS No.:932024-66-3
Molecular Formula:C₂₇H₃₆OSi
Molecular Weight:404.668
Hs Code.:

Synonyms:C₂₇H₃₆OSi

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₂₇H₃₆OSi

Chemical Property:

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Technology Process of C₂₇H₃₆OSi

There total 1 articles about C₂₇H₃₆OSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 510730-44-6
(1S,6R)-1-methyl-8-oxobicyclo[4.4.0]dec-2-ene

: 58479-61-1
tert-butylchlorodiphenylsilane

: 932024-66-3
C₂₇H₃₆OSi

Guidance literature:: (1S,6R)-1-methyl-8-oxobicyclo[4.4.0]dec-2-ene; With L-Selectride; In tetrahydrofuran; at -78 ℃;

tert-butylchlorodiphenylsilane; With 1H-imidazole; at 20 ℃; Further stages.;
DOI:10.1016/j.tetlet.2007.01.024

Reference yield: 63.0%

: 932024-66-3
C₂₇H₃₆OSi

: 932024-62-9
C₂₇H₃₄O₂Si

Guidance literature:: With potassium carbonate; In benzene; at 20 ℃;
DOI:10.1016/j.tetlet.2007.01.024

Reference yield:

: 932024-66-3
C₂₇H₃₆OSi

: 143-62-4
(+)-digitoxigenin

Guidance literature:: Multi-step reaction with 7 steps

1.1: 63 percent / K₂CO₃; org. peroxide / benzene / 20 °C

2.1: t-BuLi; lithium 2-thienylcyanocuprate / diethyl ether; tetrahydrofuran / -78 - -10 °C

2.2: 91 percent / diethyl ether; tetrahydrofuran / -78 - -30 °C

3.1: 99 percent / aq. TsOH / acetone / Heating

4.1: 82 percent / Cs₂CO₃ / acetonitrile / Heating

5.1: DIBAL-H / CH₂Cl₂ / -78 °C

5.2: KH; CS₂; MeI / tetrahydrofuran / 20 °C

5.3: n-Bu₃SnH; AIBN / benzene / Heating

6.1: 98 percent / TBAF / tetrahydrofuran / Heating

7.1: O₂; Rose bengal; DIPEA / CH₂Cl₂ / -78 °C / Irradiation

7.2: 61 percent / NaBH₄; H₂O / CH₂Cl₂ / 20 °C

With tetrabutyl ammonium fluoride; tert.-butyl lithium; oxygen; rose bengal; diisobutylaluminium hydride; potassium carbonate; caesium carbonate; toluene-4-sulfonic acid; thien-2-yl(cyano)copper lithium; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; dichloromethane; acetone; acetonitrile; benzene;
DOI:10.1016/j.tetlet.2007.01.024