rel-(3R,5S,6R)-(9E,13E)-15-acetoxy-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone

Base Information

Chemical Name:rel-(3R,5S,6R)-(9E,13E)-15-acetoxy-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone
CAS No.:108104-32-1
Molecular Formula:C₂₉H₄₀O₉S
Molecular Weight:564.697
Hs Code.:

Synonyms:rel-(3R,5S,6R)-(9E,13E)-15-acetoxy-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone

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Chemical Property of rel-(3R,5S,6R)-(9E,13E)-15-acetoxy-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone

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Technology Process of rel-(3R,5S,6R)-(9E,13E)-15-acetoxy-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone

There total 1 articles about rel-(3R,5S,6R)-(9E,13E)-15-acetoxy-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 34097-60-4
methyl benzenesulfonylacetate

: 108104-31-0
Acetic acid (2E,6E)-(R)-10-hydroxy-2,6-dimethyl-10-((S)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-undeca-2,6-dienyl ester

: 108104-32-1
rel-(3R,5S,6R)-(9E,13E)-15-acetoxy-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone

Guidance literature:: With potassium tert-butylate; In dimethyl sulfoxide; tert-butyl alcohol; for 21h; Ambient temperature;
DOI:10.1021/jo00388a008