fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate

Base Information

Chemical Name:fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate
CAS No.:431874-92-9
Molecular Formula:CF₃O₃S*C₂₀H₁₇N₃O₃Re
Molecular Weight:682.651
Hs Code.:

Synonyms:fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate

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Chemical Property of fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate

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Technology Process of fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate

There total 1 articles about fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 142939-90-0,97170-94-0
fac-tricarbonyl(2,2'-bipyridine)triflatorhenium(I)

: 106-49-0,12221-03-3
p-toluidine

: 431874-92-9
fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate

Guidance literature:: In dichloromethane; under N2, standard Schlenk techniques; ligand added to soln. of Re complex (molar ratio 1.1:1) in CH2Cl2; stirred for 1 h at room temp.; solvent removed under vac.; washed with Et2O; crystd. by slow diffusion of hexanes into CH2Cl2 soln. at -20°C; elem. anal.;
DOI:10.1021/om0110383

Reference yield: 75.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 431874-92-9
fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamine)rhenium(I) triflate

: fac-tricarbonyl(2,2'-bipyridine)(4-methylphenylamido)rhenium(I)*(tetrahydrofuran)

Guidance literature:: With KN(SiMe₃)2; In tetrahydrofuran; toluene; under N2, standard Schlenk techniques; soln. of Re complex in THF cooledto -70°C; 1 equiv. of KN(SiMe3)2 in toluene added; stirred at -7 0°C for 15 min; warmed to room temp.; volatiles removed under vac.; extd. with CH2Cl2; filtered; solvent removed under vac.; crystd. in THF-hexane; elem. anal.;
DOI:10.1021/om0110383