(S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane

Base Information

Chemical Name:(S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane
CAS No.:139259-35-1
Molecular Formula:C₁₇H₂₄O₄
Molecular Weight:292.375
Hs Code.:

Synonyms:(S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane

Chemical Property:

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Technology Process of (S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane

There total 1 articles about (S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 108404-41-7
(E)(S)-4-(3-hydroxy-2-methylpropenyl)-2,2-dimethyl[1,3]dioxolane

: 824-94-2
p-methoxybenzyl chloride

: 139259-35-1
(S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1246/cl.1992.167

Reference yield:

: 139259-35-1
(S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane

: 139259-46-4
(E)-(1S,10S)-1,5,8,8-Tetramethyl-4-phenylsulfanyl-bicyclo[8.1.0]undec-5-en-2-ol

Guidance literature:: Multi-step reaction with 13 steps

1: Zn, Cu / diethyl ether / Ambient temperature

2: 2M HCl / methanol

3: NaIO₄ / tetrahydrofuran; H₂O

4: 95.6 percent / pyridinium acetate / CH₂Cl₂

5: L-Selectride / tetrahydrofuran / -78 °C

6: 86 percent / NaH / dimethylformamide

7: LiAlH₄ / tetrahydrofuran

8: py

9: 81 percent / LiBHEt₃ / tetrahydrofuran / Ambient temperature

10: DDQ / CH₂Cl₂; H₂O

11: PCC / CH₂Cl₂

12: NaH / dimethylsulfoxide

13: 17 percent / n-BuLi, HMPA / tetrahydrofuran / -78 to 0 deg C

With pyridine; hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium periodate; lithium aluminium tetrahydride; n-butyllithium; pyridinium acetate; L-Selectride; copper; sodium hydride; lithium triethylborohydride; pyridinium chlorochromate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1246/cl.1992.167

Reference yield:

: 139259-35-1
(S)-4-[(E)-3-(4-Methoxy-benzyloxy)-2-methyl-propenyl]-2,2-dimethyl-[1,3]dioxolane

: 1-Methoxy-4-[(1S,2S)-1-methyl-2-((E)-2,2,5-trimethyl-6-phenylsulfanyl-hex-4-enyl)-cyclopropylmethoxy]-benzene

Guidance literature:: Multi-step reaction with 9 steps

1: Zn, Cu / diethyl ether / Ambient temperature

2: 2M HCl / methanol

3: NaIO₄ / tetrahydrofuran; H₂O

4: 95.6 percent / pyridinium acetate / CH₂Cl₂

5: L-Selectride / tetrahydrofuran / -78 °C

6: 86 percent / NaH / dimethylformamide

7: LiAlH₄ / tetrahydrofuran

8: py

9: 81 percent / LiBHEt₃ / tetrahydrofuran / Ambient temperature

With pyridine; hydrogenchloride; sodium periodate; lithium aluminium tetrahydride; pyridinium acetate; L-Selectride; copper; sodium hydride; lithium triethylborohydride; zinc; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1246/cl.1992.167