((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₆H₂(NO₂)3)(Cl)^(1-)=[((C₆H₅)3P)2N][Au(C₆H₂(NO₂)3)(Cl)]

Base Information

• Chemical Name: ((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₆H₂(NO₂)3)(Cl)^(1-)=[((C₆H₅)3P)2N][Au(C₆H₂(NO₂)3)(Cl)]
• CAS No.: 191722-95-9
• Molecular Formula: C₆H₂AuClN₃O₆*C₃₆H₃₀NP₂
• Molecular Weight: 983.106
• Mol file: 191722-95-9.mol

Synonyms:((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₆H₂(NO₂)3)(Cl)^(1-)=[((C₆H₅)3P)2N][Au(C₆H₂(NO₂)3)(Cl)]

Chemical Property of ((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₆H₂(NO₂)3)(Cl)^(1-)=[((C₆H₅)3P)2N][Au(C₆H₂(NO₂)3)(Cl)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₆H₂(NO₂)3)(Cl)^(1-)=[((C₆H₅)3P)2N][Au(C₆H₂(NO₂)3)(Cl)]

There total 1 articles about ((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₆H₂(NO₂)3)(Cl)^(1-)=[((C₆H₅)3P)2N][Au(C₆H₂(NO₂)3)(Cl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

bis(triphenylphosphine)nitrogen gold dichloride (106402-58-8) + bis(2,4,6-trinitrophenyl)mercury (124051-89-4) → ((C6H5)3P)2N(1+)*Au(C6H2(NO2)3)(Cl)(1-)=[((C6H5)3P)2N][Au(C6H2(NO2)3)(Cl)] (191722-95-9)

Guidance literature:

With Me₄NCl; In dichloromethane; acetone; refluxing (5 h), evapn. (room temp.), CH2Cl2 addn., refluxing (15 min); filtering (MgSO4), pptn. on concg. (vac.) and EtOH addn., filtering, washing (EtOH, Et2O), drying, recrystn. (CH2Cl2 / EtOH); elem. anal.;

DOI:10.1021/om970106b

Reference yield: 79.0%

((C6H5)3P)2N(1+)*Au(C6H2(NO2)3)(Cl)(1-)=[((C6H5)3P)2N][Au(C6H2(NO2)3)(Cl)] (191722-95-9) + hydrogen sulfide (7783-06-4) → ((C6H5)3P)2N(1+)*Au(C6H2(NO2)3)(SH)(1-)=[((C6H5)3P)2N][Au(C6H2(NO2)3)(SH)] (191798-27-3)

Guidance literature:

With Et₂NH; In dichloromethane; H2S-bubbling; pptn. on Et2O addn., filtering, washing (H2O, Et2O), drying; elem. anal.;

DOI:10.1021/om970106b

Reference yield: 56.0%

((C6H5)3P)2N(1+)*Au(C6H2(NO2)3)(Cl)(1-)=[((C6H5)3P)2N][Au(C6H2(NO2)3)(Cl)] (191722-95-9) + acetylene (74-86-2,25067-58-7) → Au(C6H2(NO2)3)C2H(1-)*((C6H5)3P)2N(1+)=Au(C6H2(NO2)3)C2H(((C6H5)3P)2N) (277303-36-3)

Guidance literature:

With thallium acetylacetonate; In acetone; byproducts: TlCl; a soln. of Tl(acac) and Au-complex was stirred for 40 min, filtd. through Celite, C2H2 was bubbled through soln. for 30 min; filtd. through anhyd. MgSO4, concd., Et2O added, ppt. collected; elem. anal.;

DOI:10.1021/om9910322

upstream raw materials:

bis(triphenylphosphine)nitrogen gold dichloride

bis(2,4,6-trinitrophenyl)mercury

Downstream raw materials:

Au(C₆H₂(NO₂)3)C₂H^(1-)*((C₆H₅)3P)2N⁽¹⁺⁾=Au(C₆H₂(NO₂)3)C₂H(((C₆H₅)3P)2N)

((C₆H₅)3P)2N⁽¹⁺⁾*Au(C₆H₂(NO₂)3)(SH)^(1-)=[((C₆H₅)3P)2N][Au(C₆H₂(NO₂)3)(SH)]