dihydridoiridium(CO)(SiMe₂Ph)(P(p-tolyl)3)2

Base Information

• Chemical Name: dihydridoiridium(CO)(SiMe₂Ph)(P(p-tolyl)3)2
• CAS No.: 115338-94-8
• Molecular Formula: C₅₁H₅₅IrOP₂Si
• Molecular Weight: 966.25
• Mol file: 115338-94-8.mol

Synonyms:dihydridoiridium(CO)(SiMe₂Ph)(P(p-tolyl)3)2

Chemical Property of dihydridoiridium(CO)(SiMe₂Ph)(P(p-tolyl)3)2

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of dihydridoiridium(CO)(SiMe₂Ph)(P(p-tolyl)3)2

There total 4 articles about dihydridoiridium(CO)(SiMe₂Ph)(P(p-tolyl)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-CH3OIr(CO)(P(p-tolyl)3)2 (115338-91-5) + trimethoxysilane (2487-90-3) → dihydridoiridium(CO)(SiMe2Ph)(P(p-tolyl)3)2 (115338-94-8) + tetramethylorthosilicate (681-84-5)

Guidance literature:

In cyclohexane; stopped flow apparatus; Change in absorbance at 365.7 nm is measured.; Kinetics;

DOI:10.1021/om00099a007

Reference yield:

trans-CH3OIr(CO)(P(p-tolyl)3)2 (115338-91-5) + HSiPh3 (789-25-3) → dihydridoiridium(CO)(SiMe2Ph)(P(p-tolyl)3)2 (115338-94-8) + methoxy-triphenyl-silane (1829-41-0)

Guidance literature:

In tetrahydrofuran-d8; THF-d8 is condensed into an NMR tube contg. the alkoxy complex and triphenylsilane (drybox, Ar). The tube is removed from liquid N2, and spectra are taken at different temps. Products are formed after warming to 23°C.; NMR;

DOI:10.1021/om00099a007

Reference yield:

trans-CH3OIr(CO)(P(p-tolyl)3)2 (115338-91-5) + Dimethylphenylsilane (766-77-8) → dihydridoiridium(CO)(SiMe2Ph)(P(p-tolyl)3)2 (115338-94-8) + methoxydimethylphenylsilane (17881-88-8)

Guidance literature:

In benzene; HSiMe2Ph is condensed in to a flask contg. a degassed suspn. of alkoxy complex (drybox, under Ar); reaction time 16 h after thawing; collection of volatile products; NMR;

DOI:10.1021/om00099a007

upstream raw materials:

trans-C₆H₅OIr(CO)(P(p-tolyl)3)2

Dimethylphenylsilane

trans-CH₃OIr(CO)(P(p-tolyl)3)2

trimethoxysilane