Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Base Information

Chemical Name:Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester
CAS No.:216978-74-4
Molecular Formula:C₁₇H₂₈O₄
Molecular Weight:296.407
Hs Code.:

Synonyms:Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

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Technology Process of Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

There total 9 articles about Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 107-30-2
chloromethyl methyl ether

: 216978-73-3
1-Acetoxymethyl-5-(1-hydroxyprop-2-enyl)-2,6,6-trimethylcyclohex-1-ene

: 216978-74-4
Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; for 14h; Ambient temperature;
DOI:10.1039/a805268i

Reference yield:

: 35044-52-1
ethyl 2-acetyl-3-methylbut-2-enoate

: 216978-74-4
Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 98 percent / tetrahydrofuran / Ambient temperature

2: 92 percent / DIBAL-H / toluene / -60 °C

3: 93 percent / PTSA / benzene / 65 °C

4: 95 percent / Et₃N, DMAP / CH₂Cl₂ / 18 h / Ambient temperature

5: 79 percent / BF₃*OEt₂ / toluene / 1.) -78 deg C, 5 min, 2.) -78 deg C, 10 h

6: 72 percent / tetrahydrofuran / 1.) -78 deg C, 1 h, 2.) r.t., 1 h

7: 91 percent / Hunig's base / CH₂Cl₂ / 14 h / Ambient temperature

With dmap; boron trifluoride diethyl etherate; diisobutylaluminium hydride; toluene-4-sulfonic acid; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; toluene; benzene;
DOI:10.1039/a805268i

Reference yield:

: 4412-05-9
2-isopropenyl-3-methyl-crotonic acid

: 216978-74-4
Acetic acid 5-(1-methoxymethoxy-allyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 73 percent / K₂CO₃ / acetone / 24 h / Ambient temperature

2: 92 percent / DIBAL-H / toluene / 2 h / -60 °C

3: 95 percent / Et₃N, DMAP / CH₂Cl₂ / 18 h / Ambient temperature

4: 79 percent / BF₃*OEt₂ / toluene / 1.) -78 deg C, 5 min, 2.) -78 deg C, 10 h

5: 72 percent / tetrahydrofuran / 1.) -78 deg C, 1 h, 2.) r.t., 1 h

6: 91 percent / Hunig's base / CH₂Cl₂ / 14 h / Ambient temperature

With dmap; boron trifluoride diethyl etherate; diisobutylaluminium hydride; potassium carbonate; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; acetone; toluene;
DOI:10.1039/a805268i