Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

Base Information

Chemical Name:Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester
CAS No.:116612-10-3
Molecular Formula:C₃₆H₅₀O₃Si₂
Molecular Weight:586.962
Hs Code.:

Synonyms:Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

Suppliers and Price of Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

There total 25 articles about Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 116612-09-0
Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-(2-oxo-ethyl)-deca-4,7-dienyl ester

: C₁₂H₂₅LiSi₂

: 116612-10-3
Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

Guidance literature:: With titanium(IV) isopropylate; In tetrahydrofuran; at -78 - 25 ℃;
DOI:10.1016/S0040-4039(00)80183-5

Reference yield:

: 101339-96-2
(2E,5Z,8Z)-2,5,8-undecatrien-1-ol

: 116612-10-3
Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((Z)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

Guidance literature:: Multi-step reaction with 12 steps

1: 85 percent / D-(-)-diethyl tartrate, tert-butyl hydroperoxide, Ti(OPri)4 / CH₂Cl₂ / 10 h / -20 °C

2: 60 percent

3: pyridinium p-toluenesulphonate / CH₂Cl₂

4: 85 percent / BF_3.OEt₂

5: pyridine

6: cond. AcOH / methanol

7: imidazol / DMAP / dimethylformamide / 20 h

8: p-toluenesulfonic acid / methanol

9: 93 percent / Lindlar

10: 81 percent / Ti(OC₃H₇)4,TBHP,L-(+)-DET / CH₂Cl₂ / 24 h / -20 °C

11: periodic acid / diethyl ether / 0.5 h / Ambient temperature

12: 85 percent / Ti(OPri)4 / tetrahydrofuran / -78 - 25 °C

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate; diethyl (2R,3R)-tartrate; Ti(OC₃H₇)4,TBHP,L-(+)-DET; boron trifluoride diethyl etherate; acetic acid; periodic acid; dmap; Lindlar's catalyst; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)80183-5

Reference yield:

: 101339-96-2
(2E,5Z,8Z)-2,5,8-undecatrien-1-ol

: 116612-10-3,116612-12-5
Acetic acid (4Z,7Z)-(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-((E)-5-trimethylsilanyl-pent-2-en-4-ynyl)-deca-4,7-dienyl ester

Guidance literature:: Multi-step reaction with 12 steps

1: 85 percent / D-(-)-diethyl tartrate, tert-butyl hydroperoxide, Ti(OPri)4 / CH₂Cl₂ / 10 h / -20 °C

2: 60 percent

3: pyridinium p-toluenesulphonate / CH₂Cl₂

4: 85 percent / BF_3.OEt₂

5: pyridine

6: cond. AcOH / methanol

7: imidazol / DMAP / dimethylformamide / 20 h

8: p-toluenesulfonic acid / methanol

9: 93 percent / Lindlar

10: 81 percent / Ti(OC₃H₇)4,TBHP,L-(+)-DET / CH₂Cl₂ / 24 h / -20 °C

11: periodic acid / diethyl ether / 0.5 h / Ambient temperature

12: 62 percent / HMPTA / tetrahydrofuran

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl (2S,3S)-tartrate; diethyl (2R,3R)-tartrate; Ti(OC₃H₇)4,TBHP,L-(+)-DET; boron trifluoride diethyl etherate; acetic acid; periodic acid; dmap; Lindlar's catalyst; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)80183-5