methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate

Base Information

Chemical Name:methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate
CAS No.:1313592-01-6
Molecular Formula:C₁₈H₂₁NO₇
Molecular Weight:363.367
Hs Code.:

Synonyms:methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate

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Chemical Property of methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate

Chemical Property:

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Technology Process of methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate

There total 8 articles about methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20357-22-6
2-nitro-4-methylbenzaldehyde

: 1313592-01-6
methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate

Guidance literature:: Multi-step reaction with 7 steps

1: potassium hexamethylsilazane / toluene

2: hydrogenchloride; water / acetone / Reflux

3: periodic acid / acetonitrile

4: hydrogenchloride / water / Reflux

5: lithium diisopropyl amide / tetrahydrofuran / -70 - -40 °C

6: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / Reflux

7: sodium carbonate / acetone / Reflux

With hydrogenchloride; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); water; potassium hexamethylsilazane; sodium carbonate; periodic acid; lithium diisopropyl amide; In tetrahydrofuran; tetrachloromethane; water; acetone; toluene; acetonitrile;
DOI:10.1016/j.bmc.2011.04.050

Reference yield:

: C₁₀H₁₁NO₃

: 1313592-01-6
methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate

Guidance literature:: Multi-step reaction with 6 steps

1: hydrogenchloride; water / acetone / Reflux

2: periodic acid / acetonitrile

3: hydrogenchloride / water / Reflux

4: lithium diisopropyl amide / tetrahydrofuran / -70 - -40 °C

5: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / Reflux

6: sodium carbonate / acetone / Reflux

With hydrogenchloride; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); water; sodium carbonate; periodic acid; lithium diisopropyl amide; In tetrahydrofuran; tetrachloromethane; water; acetone; acetonitrile;
DOI:10.1016/j.bmc.2011.04.050

Reference yield:

: 916845-88-0
methyl 2-(4-methyl-2-nitrophenyl)propanoate

: 1313592-01-6
methyl 1-[4-(1-methoxy-1-oxopropan-2-yl)-3-nitrobenzyl]-2-oxocyclopentanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / Reflux

2: sodium carbonate / acetone / Reflux

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); sodium carbonate; In tetrachloromethane; acetone;
DOI:10.1016/j.bmc.2011.04.050