Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester

Base Information

• Chemical Name: Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester
• CAS No.: 527680-88-2
• Molecular Formula: C₁₉H₁₈O₅S
• Molecular Weight: 358.415

Synonyms:Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester

Chemical Property of Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester

Chemical Property:

Purity/Quality:

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Technology Process of Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester

There total 3 articles about Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-tolyl 2,3-anhydro-5-O-benzoyl-1-thio-α-D-lyxofuranoside (329360-17-0) → Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester (527680-88-2) + Benzoic acid (1S,2R,4S,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester (527681-97-6)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - 20 ℃; for 2.5h;

DOI:10.1021/ja029302m

Reference yield:

benzoic acid (65-85-0,8013-63-6) → Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester (527680-88-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / diisopropyl azodicarboxylate; Ph₃P / tetrahydrofuran / 0.75 h / 0 - 20 °C

2: m-CPBA / CH₂Cl₂ / 2.5 h / -78 - 20 °C

With di-isopropyl azodicarboxylate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja029302m

Reference yield:

p-methylphenyl 1-thio-α-D-arabinofuranoside (204918-49-0) → Benzoic acid (1S,2R,4R,5S)-4-(toluene-4-sulfinyl)-3,6-dioxa-bicyclo[3.1.0]hex-2-ylmethyl ester (527680-88-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / diisopropyl azodicarboxylate; Ph₃P / tetrahydrofuran / 0.75 h / 0 - 20 °C

2: m-CPBA / CH₂Cl₂ / 2.5 h / -78 - 20 °C

With di-isopropyl azodicarboxylate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja029302m

upstream raw materials:

p-tolyl 2,3-anhydro-5-O-benzoyl-1-thio-α-D-lyxofuranoside

benzoic acid

p-methylphenyl 1-thio-α-D-arabinofuranoside

Downstream raw materials:

methyl 5-O-benzoyl-(2,3-anhydro-β-D-lyxofuranosyl)-2,3-di-O-benzyl-α-D-arabinofuranoside

n-octyl 2,3-anhydro-5-O-benzoyl-β-D-lyxofuranoside

methyl 5-O-{3,5-di-O-(2-O-[2,3-anhydro-5-O-benzoyl-β-D-arabinofuranosyl]-3,5-di-O-benzyl-α-D-arabinofuranosyl)-2-O-benzyl-α-D-arabinofuranosyl}-2,3-di-O-benzyl-α-D-arabinofuranoside

1-(2,3-anhydro-5-O-benzoyl-β-D-lyxofuranosyl)uracil

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