1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

Base Information

Chemical Name:1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol
CAS No.:122777-38-2
Molecular Formula:C₂₅H₂₉N₃O₄
Molecular Weight:435.523
Hs Code.:

Synonyms:1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

Suppliers and Price of 1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

There total 10 articles about 1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 127213-13-2,133646-23-8,133646-24-9
1D-(1,3/2,4)-1,2-di-O-benzyl-3-O-(methanesulfonyl)-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol

: 122777-38-2
1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

Guidance literature:: With sodium azide; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 100 ℃;
DOI:10.1021/jo00009a009

Reference yield:

: 110-87-2
3,4-dihydro-2H-pyran

: 122777-38-2
1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

Guidance literature:: Multi-step reaction with 4 steps

1: 96 percent / pyridinium p-toluenesulphonate / CH₂Cl₂

2: MeONa / methanol

3: pyridine / 50 °C

4: NaN₃ / hexamethylphosphoric acid triamide / 100 °C

With sodium azide; sodium methylate; pyridinium p-toluenesulfonate; In pyridine; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1039/c39890000436

Reference yield:

: 136458-74-7,136458-76-9,122777-36-0
2L-(2,4/3)-2-O-acetyl-3,4-di-O-benzyl-2,3,4-trihydroxy-5-cyclohexen-1-one

: 122777-38-2
1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol

Guidance literature:: Multi-step reaction with 5 steps

1: NaBH₄, CeCl₃*7H₂O / methanol / 0 °C

2: 96 percent / pyridinium p-toluenesulphonate / CH₂Cl₂

3: MeONa / methanol

4: pyridine / 50 °C

5: NaN₃ / hexamethylphosphoric acid triamide / 100 °C

With sodium tetrahydroborate; sodium azide; cerium(III) chloride; sodium methylate; pyridinium p-toluenesulfonate; In pyridine; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1039/c39890000436