N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine

Base Information

Chemical Name:N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine
CAS No.:86885-02-1
Molecular Formula:C₃₃H₄₅NOSSi
Molecular Weight:531.878
Hs Code.:

Synonyms:N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine

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Technology Process of N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine

There total 1 articles about N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 86885-01-0
C₃₃H₄₃NOSSi

: 86885-02-1
N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine

Guidance literature:: With sodium cyanoborohydride; trifluoroacetic acid; In tetrahydrofuran; for 2.5h; Ambient temperature;
DOI:10.1021/jo00168a032

Reference yield:

: 86885-02-1
N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine

: 13618-93-4
indolizidine

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Borane, 2.) aqueous NaOH, 30percent aqueous H₂O₂ / 1.) THF, room temp., 1 h, 2.) THF/methanol, room temp. 30 min.

2: 77 percent / (n-Bu)4NF, n-propylamine / tetrahydrofuran / 1.25 h / Ambient temperature

3: 4-(Dimethylamino)pyridine / CH₂Cl₂ / 0.5 h / 0 °C

4: 1.) Trimethylsilyl iodide, 2.) Na₂CO₃, Na₂SO₃, trifluoroacetic acid / CDCl₃; D₂O / 0.08 h / Ambient temperature

With propylamine; dmap; sodium hydroxide; trimethylsilyl iodide; borane; tetrabutyl ammonium fluoride; dihydrogen peroxide; sodium carbonate; trifluoroacetic acid; sodium sulfite; In tetrahydrofuran; chloroform-d1; dichloromethane; water-d2;
DOI:10.1021/jo00168a032

Reference yield:

: 86885-02-1
N-{1-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-pent-4-enyl}-S-trityl-thiohydroxylamine

: 86885-04-3
4-Tritylsulfanylamino-octane-1,8-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Borane, 2.) aqueous NaOH, 30percent aqueous H₂O₂ / 1.) THF, room temp., 1 h, 2.) THF/methanol, room temp. 30 min.

2: 77 percent / (n-Bu)4NF, n-propylamine / tetrahydrofuran / 1.25 h / Ambient temperature

With propylamine; sodium hydroxide; borane; tetrabutyl ammonium fluoride; dihydrogen peroxide; In tetrahydrofuran;
DOI:10.1021/jo00168a032