carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

Base Information

Chemical Name:carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester
CAS No.:848893-30-1
Molecular Formula:C₃₁H₄₄O₇Si₂
Molecular Weight:584.857
Hs Code.:

carbonic acid allyl ester 4-(<i>tert</i>-butyl-dimethyl-silanyloxy)-2-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

Synonyms:carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

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Chemical Property of carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

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Technology Process of carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

There total 5 articles about carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 848893-29-8
2-O-tert-butyldimethylsilyl-5-O-tert-butyldiphenylsilyl-D-ribono-1,4-lactone

: 2937-50-0
Allyl chloroformate

: 848893-30-1
carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

Guidance literature:: With pyridine; In acetonitrile; at 0 ℃; for 1.75h;
DOI:10.1016/j.tetasy.2004.12.008

Reference yield:

: 134877-40-0
3,4-O-benzylidene-D-ribonic-δ-lactone

: 848893-30-1
carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / pyridine; DMAP / 45 h / 20 °C

2: 97 percent / H₂ / Pd/C / ethyl acetate / 8 h

3: 80 percent / pyridine; Et₃N / CH₂Cl₂ / 16 h

4: 84 percent / pyridine / acetonitrile / 1.75 h / 0 °C

With pyridine; dmap; hydrogen; triethylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1016/j.tetasy.2004.12.008

Reference yield:

: 5336-08-3
D-Ribono-1,4-lactone

: 848893-30-1
carbonic acid allyl ester 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-tetrahydro-furan-3-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / aq. HCl / 7 h

2: 95 percent / pyridine; DMAP / 45 h / 20 °C

3: 97 percent / H₂ / Pd/C / ethyl acetate / 8 h

4: 80 percent / pyridine; Et₃N / CH₂Cl₂ / 16 h

5: 84 percent / pyridine / acetonitrile / 1.75 h / 0 °C

With pyridine; hydrogenchloride; dmap; hydrogen; triethylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1016/j.tetasy.2004.12.008