C₃₃H₅₂O₉Si

Base Information

Chemical Name:C₃₃H₅₂O₉Si
CAS No.:245736-35-0
Molecular Formula:C₃₃H₅₂O₉Si
Molecular Weight:620.856
Hs Code.:

C<sub>33</sub>H<sub>52</sub>O<sub>9</sub>Si

Synonyms:C₃₃H₅₂O₉Si

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Chemical Property of C₃₃H₅₂O₉Si

Chemical Property:

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Technology Process of C₃₃H₅₂O₉Si

There total 17 articles about C₃₃H₅₂O₉Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 245736-35-0
C₃₃H₅₂O₉Si

Guidance literature:: Multi-step reaction with 16 steps

1: NaH / dimethylformamide; tetrahydrofuran

2: HCl / methanol; diethyl ether / 0 °C

3: (COCl)2, DMSO, i-Pr₂NEt / -78 - -30 °C

4: 73 percent / TiCl₂(O-i-Pr)2 / CH₂Cl₂ / -78 - 0 °C

5: Et₂BOMe, NaBH₄ / tetrahydrofuran; methanol / -78 °C

6: HCl

7: DIBAL-H / CH₂Cl₂ / -78 °C

8: 1.) Bu₂BOTf, i-Pr₂NEt / 1.) CH₂Cl₂, 0 deg C, 2.) CH₂Cl₂, -78 deg C

9: 100 percent / (COCl)2, DMSO, i-Pr₂NEt / -78 - 0 °C

10: 82 percent / TsOH / acetonitrile / -22 °C

11: 100 percent / (COCl)2, DMSO, Et₃N / -78 - 0 °C

12: LDA / 1 h / -78 °C

13: LiOOH / tetrahydrofuran; dimethylformamide; H₂O / 0 - 23 °C

14: aq. OsO₄, NMO / tetrahydrofuran; 2-methyl-propan-2-ol

15: aq. NaIO₄, NaHCO₃ / tetrahydrofuran; 2-methyl-propan-2-ol

16: 1.) Et₃N, 2.) Et₃NHOAc

With hydrogenchloride; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; titanium(IV) dichlorodiisopropylate; oxalyl dichloride; lithium hydroperoxide; di-n-butylboryl trifluoromethanesulfonate; diethyl methoxy borane; triethylammonium acetate; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; tert-butyl alcohol;
DOI:10.1021/ja990789h

Reference yield:

: (R)-2-(4-Methoxy-benzyloxy)-hex-5-enal

: 245736-35-0
C₃₃H₅₂O₉Si

Guidance literature:: Multi-step reaction with 13 steps

1: 73 percent / TiCl₂(O-i-Pr)2 / CH₂Cl₂ / -78 - 0 °C

2: Et₂BOMe, NaBH₄ / tetrahydrofuran; methanol / -78 °C

3: HCl

4: DIBAL-H / CH₂Cl₂ / -78 °C

5: 1.) Bu₂BOTf, i-Pr₂NEt / 1.) CH₂Cl₂, 0 deg C, 2.) CH₂Cl₂, -78 deg C

6: 100 percent / (COCl)2, DMSO, i-Pr₂NEt / -78 - 0 °C

7: 82 percent / TsOH / acetonitrile / -22 °C

8: 100 percent / (COCl)2, DMSO, Et₃N / -78 - 0 °C

9: LDA / 1 h / -78 °C

10: LiOOH / tetrahydrofuran; dimethylformamide; H₂O / 0 - 23 °C

11: aq. OsO₄, NMO / tetrahydrofuran; 2-methyl-propan-2-ol

12: aq. NaIO₄, NaHCO₃ / tetrahydrofuran; 2-methyl-propan-2-ol

13: 1.) Et₃N, 2.) Et₃NHOAc

With hydrogenchloride; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; titanium(IV) dichlorodiisopropylate; oxalyl dichloride; lithium hydroperoxide; di-n-butylboryl trifluoromethanesulfonate; diethyl methoxy borane; triethylammonium acetate; diisobutylaluminium hydride; sodium hydrogencarbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; tert-butyl alcohol;
DOI:10.1021/ja990789h

Reference yield:

: 245736-20-3
(R)-2-(4-Methoxy-benzyloxy)-hex-5-en-1-ol

: 245736-35-0
C₃₃H₅₂O₉Si

Guidance literature:: Multi-step reaction with 14 steps

1: (COCl)2, DMSO, i-Pr₂NEt / -78 - -30 °C

2: 73 percent / TiCl₂(O-i-Pr)2 / CH₂Cl₂ / -78 - 0 °C

3: Et₂BOMe, NaBH₄ / tetrahydrofuran; methanol / -78 °C

4: HCl

5: DIBAL-H / CH₂Cl₂ / -78 °C

6: 1.) Bu₂BOTf, i-Pr₂NEt / 1.) CH₂Cl₂, 0 deg C, 2.) CH₂Cl₂, -78 deg C

7: 100 percent / (COCl)2, DMSO, i-Pr₂NEt / -78 - 0 °C

8: 82 percent / TsOH / acetonitrile / -22 °C

9: 100 percent / (COCl)2, DMSO, Et₃N / -78 - 0 °C

10: LDA / 1 h / -78 °C

11: LiOOH / tetrahydrofuran; dimethylformamide; H₂O / 0 - 23 °C

12: aq. OsO₄, NMO / tetrahydrofuran; 2-methyl-propan-2-ol

13: aq. NaIO₄, NaHCO₃ / tetrahydrofuran; 2-methyl-propan-2-ol

14: 1.) Et₃N, 2.) Et₃NHOAc

With hydrogenchloride; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; titanium(IV) dichlorodiisopropylate; oxalyl dichloride; lithium hydroperoxide; di-n-butylboryl trifluoromethanesulfonate; diethyl methoxy borane; triethylammonium acetate; diisobutylaluminium hydride; sodium hydrogencarbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; tert-butyl alcohol;
DOI:10.1021/ja990789h