methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid

Base Information

Chemical Name:methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid
CAS No.:1520095-00-4
Molecular Formula:C₂₂H₂₅O₁₂P
Molecular Weight:512.407
Hs Code.:

Synonyms:methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid

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Chemical Property of methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid

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Technology Process of methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid

There total 6 articles about methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1520094-99-8
methyl 2,3-di-O-benzoyl-4-O-(dibenzyloxyphosphoryl)-L-glycero-α-D-manno-heptopyranoside

: 1520095-00-4
methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid

Guidance literature:: With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 2h;
DOI:10.1021/jo402312x

Reference yield:

: 127642-33-5,686299-10-5
methyl L-glycero-α-D-manno-heptopyranoside

: 1520095-00-4
methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid

Guidance literature:: Multi-step reaction with 6 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 2.5 h / -55 - 20 °C

2.1: camphor-10-sulfonic acid / dichloromethane / 0.5 h / 20 °C

3.1: 1H-tetrazole / dichloromethane; acetonitrile / 0.75 h / 20 °C

3.2: 1.25 h / -78 °C

4.1: camphor-10-sulfonic acid; water / dichloromethane / 1 h / 20 °C

4.2: 20 °C

5.1: triethylamine tris(hydrogen fluoride) / dichloromethane / 0 °C

6.1: palladium 10% on activated carbon; hydrogen / methanol / 2 h / 20 °C

With 1H-imidazole; 1H-tetrazole; palladium 10% on activated carbon; camphor-10-sulfonic acid; water; hydrogen; triethylamine tris(hydrogen fluoride); In methanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo402312x

Reference yield:

: 1520094-68-1
methyl 6,7-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-Lglycero-α-D-manno-heptopyranoside

: 1520095-00-4
methyl 2,3-di-O-benzoyl-L-glycero-α-D-manno-heptopyranoside4-O-phosphoric acid

Guidance literature:: Multi-step reaction with 5 steps

1.1: camphor-10-sulfonic acid / dichloromethane / 0.5 h / 20 °C

2.1: 1H-tetrazole / dichloromethane; acetonitrile / 0.75 h / 20 °C

2.2: 1.25 h / -78 °C

3.1: camphor-10-sulfonic acid; water / dichloromethane / 1 h / 20 °C

3.2: 20 °C

4.1: triethylamine tris(hydrogen fluoride) / dichloromethane / 0 °C

5.1: palladium 10% on activated carbon; hydrogen / methanol / 2 h / 20 °C

With 1H-tetrazole; palladium 10% on activated carbon; camphor-10-sulfonic acid; water; hydrogen; triethylamine tris(hydrogen fluoride); In methanol; dichloromethane; acetonitrile;
DOI:10.1021/jo402312x