ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

Base Information

Chemical Name:ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate
CAS No.:123887-03-6
Molecular Formula:C₁₈H₃₀O₄
Molecular Weight:310.434
Hs Code.:

Synonyms:ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

Suppliers and Price of ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

There total 12 articles about ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.1%

: 123886-97-5
3-[(1S,3R,4S,5R)-3-(2-Acetoxy-ethyl)-5-hydroxy-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

: 123887-03-6
ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 12h; Ambient temperature;
DOI:10.1248/cpb.36.4722

Reference yield: 88.0%

: 123886-97-5
3-[(1S,3R,4S,5R)-3-(2-Acetoxy-ethyl)-5-hydroxy-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

: 65-85-0,8013-63-6
benzoic acid

: 123887-03-6
ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

: 123887-04-7
ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 15h; Ambient temperature;
DOI:10.1248/cpb.36.4722

Reference yield:

: 123886-96-4
3-[(1S,3R,4S,5R)-5-Benzyloxycarbonyloxy-2,2,4-trimethyl-3-(3-oxo-butyl)-cyclohexyl]-propionic acid ethyl ester

: 123887-03-6
ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

Guidance literature:: Multi-step reaction with 3 steps

1: 82.6 percent / mCPBA / 1,2-dichloro-ethane / 44 h / 55 °C

2: 89.5 percent / hydrogen / 10percent Pd-C / ethanol / 0.5 h / Ambient temperature

3: 89.1 percent / diethyl azodicarboxylate, triphenylphosphine / tetrahydrofuran / 12 h / Ambient temperature

With hydrogen; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In tetrahydrofuran; ethanol; 1,2-dichloro-ethane;
DOI:10.1248/cpb.36.4722