8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Base Information

Chemical Name:8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside
CAS No.:180336-12-3
Molecular Formula:C₅₄H₆₇NO₁₄
Molecular Weight:954.124
Hs Code.:

Synonyms:8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

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Chemical Property of 8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

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Technology Process of 8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

There total 1 articles about 8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 77790-47-7
2-O-acetyl-3,4,6-tri-O-benzyl-α-D-galactopyranosyl bromide

: 71048-95-8
ω-methoxycarbonyloctyl 2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 180336-12-3
8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Guidance literature:: With calcium sulfate; 4 A molecular sieve; mercury(II) cyanide; In nitromethane; toluene; for 2h;
DOI:10.1016/0008-6215(96)00047-X

Reference yield: 93.0%

: 180336-12-3
8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 98856-37-2
8-methoxycarbonyloctyl 3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Guidance literature:: With sodium methylate; In methanol; dichloromethane; for 20h;
DOI:10.1016/0008-6215(96)00047-X

Reference yield:

: 180336-12-3
8-methoxycarbonyloctyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 98807-72-8
8-methoxycarbonyloctyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-lyxo-hexopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: 93 percent / NaOMe / methanol; CH₂Cl₂ / 20 h

2.1: imidazole; sodium hydride / tetrahydrofuran / 0.5 h / Heating

2.2: tetrahydrofuran / 0.5 h / Heating

2.3: 33 percent / tetrahydrofuran / 0.5 h / Heating

3.1: 75 percent / α,α'-azobisisobutyronitrile; tributyltin hydride / toluene / 2 h / 80 °C

With 1H-imidazole; azobisisobutyronitrile; tri-n-butyl-tin hydride; sodium methylate; sodium hydride; In tetrahydrofuran; methanol; dichloromethane; toluene; 1.1: Deacetylation / 2.1: Metallation / 2.2: Addition / 2.3: Methylation / 3.1: Reduction;
DOI:10.1016/0008-6215(96)00047-X