Technology Process of [(C5(C6H5)5)Fe(C5H4CH2CH2CH2COOH)]
There total 1 articles about [(C5(C6H5)5)Fe(C5H4CH2CH2CH2COOH)] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
HgCl2; Zn; HCl;
In
water; toluene;
(Ar); using Schlenk techniquus; addn. of Zn dust and HgCl2 to (C5Me5)Fe(C5H4COCH2CH2COOH) and toluene, vigorous stirring with addn. of H2O and then HCl via syringe, reflux for 24 h; cooling to room temp., filtration, transferring of mother liquor into sepn. funnel, removal of aq. phase, washing of org. phase with brine, drying over Na2SO4, filtration, evapn. of solvent under reduced pressure, flash chromy. (SiO2, hexanes/Et2O 2/1);
DOI:10.1021/om2002206
- Guidance literature:
-
With
trifluoroacetic anhydride;
In
tetrachloromethane;
using Schlenk techniquus; charging of (C5Ph5)Fe(C5H4(CH2)3COOH) and CCl4to flask, wrapping with Al foil, bubbling with Ar for 10 min, cooling t o 0°C, addn. of (CF3CO)2O via syringe, stirring at 50°C overnight; transferring into funnel, sepn. between 10% NaOH and CH2Cl2, washing of org. phase with brine, drying over Na2SO4, filtration, removal of volatiles under reduced pressure, flash chromy. (SiO2, hexanes/CH2Cl2/Et2O 20/20/1);
DOI:10.1021/om2002206
![[(C<sub>5</sub>(C<sub>6</sub>H<sub>5</sub>)5)Fe(C<sub>5</sub>H<sub>4</sub>COCH<sub>2</sub>CH<sub>2</sub>COOH)]](/Databaselist/images/loading.webp)
