(CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)

Base Information

Chemical Name:(CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)
CAS No.:144812-13-5
Molecular Formula:C₁₆H₂₅O₄P₂Re
Molecular Weight:529.527
Hs Code.:

(CO)3(P(CH<sub>3</sub>)3)2Re(OC<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)

Synonyms:(CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)

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Chemical Property of (CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)

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Technology Process of (CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)

There total 2 articles about (CO)3(P(CH₃)3)2Re(OC₆H₄CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 106-44-5
p-cresol

: 138695-27-9
fac-Re(CO)3(PMe₃)2(OSO₂CF₃)

: 144812-13-5
(CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)

Guidance literature:: With KN(Si(CH₃)3)2; In tetrahydrofuran; mixing of p-cresol and KN(TMS)2; addn. of THF; stirring at room temperature for 20 min; addn. to Re-compound; stirring for 2 days at room temperature; inert atm.;; removal of volatiles under vac.; dissolving in toluene; filtration; removal of toluene in vac.;;
DOI:10.1021/om00027a031

Reference yield: 61.0%

: 138695-26-8
Re(CO)3(P(C₆H₅)3)2(OC₆H₄CH₃)

: 594-09-2
trimethylphosphane

: 144812-13-5
(CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)

Guidance literature:: In benzene; byproducts: P(C6H5)3; charging a bomb with Re-compound in C6H6; condensation of P(CH3)3 into the bomb at -196°C; heating to 45°C overnight; inert atm.;; concn.; pptn. by addn. of hexanes; filtration; washing with hexane; dissolving in toluene; layering with pentane; cooling to -40°C overnight; crystallization; filtration; washing with hexane; drying in high vac. for 12 h; elem. anal.;;
DOI:10.1021/om00027a031

Reference yield: 52.0%

: 144812-13-5
(CO)3(P(CH₃)3)2Re(OC₆H₄CH₃)

: 138695-32-6
(CO)3(P(CH₃)3)2Re(S(S)COC₆H₄CH₃)

Guidance literature:: With CS₂; In benzene; bomb charged with Re-compd. and solvent in a drybox, CS2 condensed into the bomb, heated for 7 days at 140°C, color changed, cooled to room temp;; monitored by 31P-NMR, evapd. (vac.), dissolved in toluene, diffusion of pentane vapor into soln. at room temp., crystn. within 4 days, washed (pentane), dried ; elem. anal.;