C₆₅H₁₁₈O₁₂S₂Si₂

Base Information

Chemical Name:C₆₅H₁₁₈O₁₂S₂Si₂
CAS No.:1054638-64-0
Molecular Formula:C₆₅H₁₁₈O₁₂S₂Si₂
Molecular Weight:1211.95
Hs Code.:

C<sub>65</sub>H<sub>118</sub>O<sub>12</sub>S<sub>2</sub>Si<sub>2</sub>

Synonyms:C₆₅H₁₁₈O₁₂S₂Si₂

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Chemical Property of C₆₅H₁₁₈O₁₂S₂Si₂

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Technology Process of C₆₅H₁₁₈O₁₂S₂Si₂

There total 35 articles about C₆₅H₁₁₈O₁₂S₂Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: C₇₇H₁₄₈O₁₂S₂Si₅

: 1054638-64-0
C₆₅H₁₁₈O₁₂S₂Si₂

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃;
DOI:10.1002/anie.200461802

Reference yield:

: (2E,6E)-9-(1R,5R)-6,8-Dioxa-bicyclo[3.2.1]oct-5-yl-6-methyl-nona-2,6-dien-1-ol

: 1054638-64-0
C₆₅H₁₁₈O₁₂S₂Si₂

Guidance literature:: Multi-step reaction with 15 steps

1.1: 83 percent / t-BuCOOH; Ti(i-PrO)4; (+)-diethyl tartrate / 4 Angstroem molecular sieves / CH₂Cl₂ / -20 °C

2.1: SO₃*py; Et₃N; DMSO / CH₂Cl₂ / 20 °C

3.1: tetrahydrofuran / -40 °C

4.1: NaAlH₂(OCH₂CH₂OMe) / diethyl ether / -20 - 0 °C

4.2: 90 percent / aq. NaIO₄ / tetrahydrofuran / 20 °C

5.1: 91 percent / TsOH / dimethylformamide / 20 °C

6.1: OsO₄; (DHQD)2PHAL; K₃[Fe(CN)6] / K₂CO₃; MeSO₂NH₂ / H₂O; 2-methyl-propan-2-ol / 0 °C

7.1: SO₃*py; Et₃N; DMSO / 20 °C

8.1: (+)-camphorsulfonic acid / methanol / 3 h / 20 °C

8.2: 84 percent / (+)-camphorsulfonic acid / toluene / 48 h / 20 °C

9.1: pyridine / CH₂Cl₂ / 0 - 20 °C

10.1: 2,6-lutidine / CH₂Cl₂ / 0 °C

11.1: DIBAL-H / tetrahydrofuran / -78 °C

12.1: 91 percent / I₂; PPh₃; imidazole / tetrahydrofuran / 20 °C

13.1: 83 percent / n-BuLi; HMPA / tetrahydrofuran / -78 °C

14.1: t-BuLi; HMPA / tetrahydrofuran / -78 °C

15.1: 89 percent / TBAF / tetrahydrofuran / 0 °C

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; N,N,N,N,N,N-hexamethylphosphoric triamide; osmium(VIII) oxide; n-butyllithium; pyridine-SO₃ complex; tetrabutyl ammonium fluoride; iodine; tert.-butyl lithium; diisobutylaluminium hydride; toluene-4-sulfonic acid; dimethyl sulfoxide; (+)-Weinsaeure-diethylester; (+)-10-camphorsulfonic acid; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; triphenylphosphine; sodium bis(2-methoxyethoxy)aluminium dihydride; potassium hexacyanoferrate(III); Trimethylacetic acid; methanesulfonamide; 4 A molecular sieve; potassium carbonate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 1.1: Sharpless epoxidation;
DOI:10.1002/anie.200461802

Reference yield:

: 834916-65-3
(2R,3S)-3-((E)-6-(1R,5R)-6,8-Dioxa-bicyclo[3.2.1]oct-5-yl-3-methyl-hex-3-enyl)-oxirane-2-carbaldehyde

: 1054638-64-0
C₆₅H₁₁₈O₁₂S₂Si₂

Guidance literature:: Multi-step reaction with 13 steps

1.1: tetrahydrofuran / -40 °C

2.1: NaAlH₂(OCH₂CH₂OMe) / diethyl ether / -20 - 0 °C

2.2: 90 percent / aq. NaIO₄ / tetrahydrofuran / 20 °C

3.1: 91 percent / TsOH / dimethylformamide / 20 °C

4.1: OsO₄; (DHQD)2PHAL; K₃[Fe(CN)6] / K₂CO₃; MeSO₂NH₂ / H₂O; 2-methyl-propan-2-ol / 0 °C

5.1: SO₃*py; Et₃N; DMSO / 20 °C

6.1: (+)-camphorsulfonic acid / methanol / 3 h / 20 °C

6.2: 84 percent / (+)-camphorsulfonic acid / toluene / 48 h / 20 °C

7.1: pyridine / CH₂Cl₂ / 0 - 20 °C

8.1: 2,6-lutidine / CH₂Cl₂ / 0 °C

9.1: DIBAL-H / tetrahydrofuran / -78 °C

10.1: 91 percent / I₂; PPh₃; imidazole / tetrahydrofuran / 20 °C

11.1: 83 percent / n-BuLi; HMPA / tetrahydrofuran / -78 °C

12.1: t-BuLi; HMPA / tetrahydrofuran / -78 °C

13.1: 89 percent / TBAF / tetrahydrofuran / 0 °C

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; osmium(VIII) oxide; n-butyllithium; pyridine-SO₃ complex; tetrabutyl ammonium fluoride; iodine; tert.-butyl lithium; diisobutylaluminium hydride; toluene-4-sulfonic acid; dimethyl sulfoxide; (+)-10-camphorsulfonic acid; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; triphenylphosphine; sodium bis(2-methoxyethoxy)aluminium dihydride; potassium hexacyanoferrate(III); methanesulfonamide; potassium carbonate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1002/anie.200461802