(2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol

Base Information

Chemical Name:(2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol
CAS No.:213468-48-5
Molecular Formula:C₂₂H₂₈O₃Se
Molecular Weight:419.423
Hs Code.:

Synonyms:(2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol

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Chemical Property of (2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol

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Technology Process of (2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol

There total 3 articles about (2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-(E)-5-benzyloxy-4-methylpent-2-enyl(tributyl)stannane

: 213468-48-5
(2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol

Guidance literature:: Multi-step reaction with 3 steps

1: SnCl₄ / CH₂Cl₂ / -78 °C

2: tert-butyl hydroperoxide, VO(acac)2 / CH₂Cl₂ / Ambient temperature

3: 1.) NaBH₄; 2.) perchloric acid / 1.) EtOH, r.t.; 2.) CH₂Cl₂, r.t.

With tert.-butylhydroperoxide; sodium tetrahydroborate; perchloric acid; bis(acetylacetonate)oxovanadium; tin(IV) chloride; In dichloromethane;
DOI:10.3987/com-98-8161

Reference yield:

: 213468-44-1
(Z)-(2S,3S,7R)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-7-methyl-oct-5-en-3-ol

: 213468-48-5
(2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1: tert-butyl hydroperoxide, VO(acac)2 / CH₂Cl₂ / Ambient temperature

2: 1.) NaBH₄; 2.) perchloric acid / 1.) EtOH, r.t.; 2.) CH₂Cl₂, r.t.

With tert.-butylhydroperoxide; sodium tetrahydroborate; perchloric acid; bis(acetylacetonate)oxovanadium; In dichloromethane;
DOI:10.3987/com-98-8161

Reference yield:

: 1666-13-3
diphenyl diselenide

: 213468-46-3
(2S,3S)-1-[(2R,3S)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-3-(tert-butyl-dimethyl-silanyloxy)-butan-2-ol

: 213468-48-5
(2S,3S,5R)-5-((1R,2S)-3-Benzyloxy-2-methyl-1-phenylselanyl-propyl)-2-methyl-tetrahydro-furan-3-ol

Guidance literature:: With sodium tetrahydroborate; perchloric acid; Yield given. Multistep reaction; 1.) EtOH, r.t.; 2.) CH₂Cl₂, r.t.;
DOI:10.3987/com-98-8161