1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate

Base Information

Chemical Name:1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate
CAS No.:98127-02-7
Molecular Formula:C₁₈H₃₃O₆PSi
Molecular Weight:404.516
Hs Code.:

Synonyms:1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate

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Chemical Property of 1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate

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Technology Process of 1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate

There total 4 articles about 1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 41309-43-7
(2-bromovinyl)trimethylsilane

: 98127-02-7
1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) t-butyllithium, 2.) CuI

2: 1.) NaH / 1.) ether, 10 min, 2.) ether, 2 h

With copper(l) iodide; tert.-butyl lithium; sodium hydride;
DOI:10.1021/jo00221a027

Reference yield:

: 3128-06-1
5-ketohexanoic acid

: 98127-02-7
1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / SOCl₂ / benzene / 10 h / Heating

2: 1.) lithium diisopropylamide / 1.) THF, -78 deg C, 0.5 h, 2.) THF, a) -78 deg C, 4 h, b) 25 deg C, 8 h

3: 1.) t-butyllithium, 2.) CuI

4: 1.) NaH / 1.) ether, 10 min, 2.) ether, 2 h

With copper(l) iodide; thionyl chloride; tert.-butyl lithium; sodium hydride; lithium diisopropyl amide; In benzene;
DOI:10.1021/jo00221a027

Reference yield:

: 86891-79-4
methyl 3-methyl-1-oxo-2-cyclohexene-2-carboxylate

: 98127-02-7
1-carbomethoxy-6-methyl-6-<(E)-2-(trimethylsilyl)vinyl>-1-cyclohexen-2-yl diethyl phosphate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) t-butyllithium, 2.) CuI

2: 1.) NaH / 1.) ether, 10 min, 2.) ether, 2 h

With copper(l) iodide; tert.-butyl lithium; sodium hydride;
DOI:10.1021/jo00221a027