<(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide

Base Information

• Chemical Name: <(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide
• CAS No.: 32205-44-0
• Molecular Formula: C₃₀H₃₆P*I
• Molecular Weight: 554.494
• Mol file: 32205-44-0.mol

Synonyms:<(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide

Chemical Property of <(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of <(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide

There total 7 articles about <(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(E)-(E)-5,9-Dimethyl-4,8-decadien-1-yl iodide (67858-89-3) + triphenylphosphine (603-35-0) → <(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide (32205-44-0)

Guidance literature:

In benzene; for 96h; Ambient temperature;

DOI:10.1021/jo00109a026

Reference yield:

trans-geranyl bromide (6138-90-5) → <(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide (32205-44-0)

Guidance literature:

Multi-step reaction with 5 steps

1: -78 °C

2: LiAlH₄

3: pyridine

4: NaI

With pyridine; lithium aluminium tetrahydride; sodium iodide;

DOI:10.1021/ja00389a106

Reference yield:

Geraniol (106-24-1) → <(E)-5,9-Dimethyl-4,8-decadienyl>triphenylphosphonium iodide (32205-44-0)

Guidance literature:

Multi-step reaction with 6 steps

1: PBr₃

2: -78 °C

3: LiAlH₄

4: pyridine

5: NaI

With pyridine; lithium aluminium tetrahydride; phosphorus tribromide; sodium iodide;

DOI:10.1021/ja00389a106

upstream raw materials:

geranylacetic acid

triphenylphosphine

(E)-(E)-5,9-Dimethyl-4,8-decadien-1-yl iodide

trans-geranyl bromide

Downstream raw materials:

(E)-(6,10-dimethyl-5,9-undecadien-2-ylidene)triphenylphosphorane