3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone

Base Information

• Chemical Name: 3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone
• CAS No.: 96633-30-6
• Molecular Formula: C₂₈H₃₀N₂O₂S
• Molecular Weight: 458.624
• Mol file: 96633-30-6.mol

Synonyms:3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone

Chemical Property of 3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone

There total 4 articles about 3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one (96633-28-2) + toluene-4-sulfonic acid hydrazide (1576-35-8) → 3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone (96633-30-6)

Guidance literature:

With hydrogenchloride; In methanol; for 9.5h; Heating;

DOI:10.1021/jo00214a027

Reference yield:

p-Tolylaceton (2096-86-8) → 3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone (96633-30-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 54 percent / piperidine / benzene / 18 h / Heating

3: 91 percent / pyridine, 30percent H₂O₂ / CH₂Cl₂ / 1 h

4: 82 percent / conc. HCl / methanol / 9.5 h / Heating

With piperidine; pyridine; hydrogenchloride; dihydrogen peroxide; In methanol; dichloromethane; benzene;

DOI:10.1021/jo00214a027

Reference yield:

3-p-tolyl-4-phenylbuten-2-one (96633-25-9) → 3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one tosylhydrazone (96633-30-6)

Guidance literature:

Multi-step reaction with 3 steps

2: 91 percent / pyridine, 30percent H₂O₂ / CH₂Cl₂ / 1 h

3: 82 percent / conc. HCl / methanol / 9.5 h / Heating

With pyridine; hydrogenchloride; dihydrogen peroxide; In methanol; dichloromethane;

DOI:10.1021/jo00214a027

upstream raw materials:

3-p-tolyl-4-phenyl-6-methyl-3,5-heptadien-2-one

toluene-4-sulfonic acid hydrazide

p-Tolylaceton

3-p-tolyl-4-phenylbuten-2-one

Downstream raw materials:

1-phenyl-2-p-tolyl-3,5,5-trimethylcyclopentadiene

1,5,5-trimethyl-2-p-tolyl-3-phenylcyclopentadiene

3,3,7-trimethyl-5-phenyl-6-p-tolyl-3H-1,2-diazepine

1-p-tolyl-2-methyl-3-phenyl-3-isobutenylcyclopropene